TY - JOUR U1 - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed) A1 - Urdl, Katharina A1 - Weiss, Stephanie A1 - Christöfl, Petra A1 - Kandelbauer, Andreas A1 - Müller, Uwe A1 - Kern, Wolfgang T1 - Diels-Alder modified self-healing melamine resin JF - European Polymer Journal N2 - The self-healing effect of melamine-based surfaces, triggered by temperature, was investigated. The temperature triggered reversible healing chemistry, on which the self-healing effect is based, was the Diels-Alder (DA) reaction between furan and malemeide groups. Melamine-furan containing building blocks were connected by multi-functional maleimide crosslinker via a Diels-Alder (DA) reaction to giva a DA adduct. The DA adduct was then reacted with formaldehyde to form a network by conventional condensation reaction of melamine amino groups with formaldehyde. The obtained resin was characterised and used for the impregnation of paper. Impregnated papers and neat resin werde used to perform scratch-healing tests and mechanical analysis of the novel coating system. KW - thermoset KW - melamine-formaldehyde KW - furan-functionalised KW - particle KW - Diels-Alder reaction Y1 - 2020 SN - 0014-3057 SS - 0014-3057 U6 - https://doi.org/10.1016/j.eurpolymj.2020.109601 DO - https://doi.org/10.1016/j.eurpolymj.2020.109601 VL - 127 SP - 1 EP - 12 S1 - 12 PB - Elsevier CY - Amsterdam ER -