@article{OelkrugBoldriniRebner2017, author = {Oelkrug, Dieter and Boldrini, Barbara and Rebner, Karsten}, title = {Comparative Raman study of transparent and turbid materials : models and experiments in the remote sensing mode}, journal = {Analytical and bioanalytical chemistry}, volume = {409}, issn = {1618-2642}, doi = {10.1007/s00216-016-9582-0}, institution = {Life Sciences}, pages = {673 -- 681}, year = {2017}, abstract = {The influence of turbidity on the Raman signal strengths of condensed matter is theoretically analyzed and measured with laboratory - scale equipment for remote sensing. The results show the quantitative dependence of back- and forward-scattered signals on the thickness and elastic-scattering properties of matter. In the extreme situation of thin, highly turbid layers, the measured Raman signal strengths exceed their transparent analogs by more than a factor of ten. The opposite behavior is found for thick layers of low turbidity, where the presence of a small amount of scatterers leads to a decrease of the measured signal. The wide range of turbidities appearing in nature is experimentally realized with stacked polymer layers and solid/liquid dispersions, and theoretically modeled by the equation of radiative transfer using the analytical diffusion approximation or random walk simulations.}, language = {en} }