TY  - JOUR
U1  - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed)
A1  - Konrad, Alexander
A1  - Metzger, Michael
A1  - Kern, Andreas
A1  - Brecht, Marc
A1  - Meixner, Alfred
T1  - Revealing the radiative and non-radiative relaxation rates of the fluorescent dye Atto488 in a λ/2 Fabry-Pérot-resonator by spectral and time resolved measurements
JF  - Nanoscale
N2  - Using a Fabry-Pérot-microresonator with controllable cavity lengths in the λ/2-regime, we show the controlled modification of the vibronic relaxation dynamics of a fluorescent dye molecule in the spectral and time domain. By altering the photonic mode density around the fluorophores we are able to shape the fluorescence spectrum and enhance specifically the probability of the radiative transitions from the electronic excited state to distinct vibronic excited states of the electronic ground state. Analysis and correlation of the spectral and time resolved measurements by a theoretical model and a global fitting procedure allows us to reveal quantitatively the spectrally distributed radiative and non-radiative relaxation dynamics of the respective dye molecule under ambient conditions at the ensemble level.
Y1  - 2016
UN  - https://nbn-resolving.org/urn:nbn:de:bsz:rt2-opus4-10393
SN  - 2040-3364
SS  - 2040-3364
U6  - https://doi.org/10.1039/c6nr02380k
DO  - https://doi.org/10.1039/c6nr02380k
VL  - 8
IS  - 30
SP  - 14541
EP  - 14547
S1  - 7
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -