Homogeneous, monodispersed furan-melamine particles performing reversible binding and forming networks
- Homogeneous and monodispersed furan functionalised melamine-formaldehyde particles were produced. As a precursor, 2-chloro-1,3,5-triazine-2,4-diamine (Mel) was selectively substituted with 2-aminomethyl furan (Fu) units in a convenient one step reaction. The pure reaction product Fu-Mel, which was used without further purification, was reacted with formaldehyde by conventional sol-gel condensation in aqueous medium to yield chemically homogenous, spherically shaped and monodispersed particles. The particles were analysed using ATR-FT-IR, Raman, 1H and 13C NMR spectroscopy, TGA, SEM and DSC measurements. The reactivity of the furan groups located at the particle surface was studied by performing a thermoreversible Diels-Alder cycloaddition reaction with bis-maleimide coupling agents. The formed networks showed thermoreversible behaviour, which was characterised by dynamic IR and DSC measurements.
Author of HS Reutlingen | Brodbeck, Björn; Kandelbauer, Andreas |
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DOI: | https://doi.org/10.1016/j.eurpolymj.2019.04.006 |
ISSN: | 0014-3057 |
Erschienen in: | European polymer journal |
Publisher: | Elsevier |
Place of publication: | Amsterdam |
Document Type: | Journal article |
Language: | English |
Publication year: | 2019 |
Tag: | Diels-Alder reaction; furan-functionalised; melamine-formaldehyde; particle; thermoset |
Issue: | 116 |
Page Number: | 11 |
First Page: | 158 |
Last Page: | 168 |
DDC classes: | 670 Industrielle und handwerkliche Fertigung |
Open access?: | Nein |