Diels-Alder modified self-healing melamine resin
- The self-healing effect of melamine-based surfaces, triggered by temperature, was investigated. The temperature triggered reversible healing chemistry, on which the self-healing effect is based, was the Diels-Alder (DA) reaction between furan and malemeide groups. Melamine-furan containing building blocks were connected by multi-functional maleimide crosslinker via a Diels-Alder (DA) reaction to giva a DA adduct. The DA adduct was then reacted with formaldehyde to form a network by conventional condensation reaction of melamine amino groups with formaldehyde. The obtained resin was characterised and used for the impregnation of paper. Impregnated papers and neat resin werde used to perform scratch-healing tests and mechanical analysis of the novel coating system.
| Author of HS Reutlingen | Kandelbauer, Andreas |
|---|---|
| DOI: | https://doi.org/10.1016/j.eurpolymj.2020.109601 |
| ISSN: | 0014-3057 |
| Erschienen in: | European Polymer Journal |
| Publisher: | Elsevier |
| Place of publication: | Amsterdam |
| Document Type: | Journal article |
| Language: | English |
| Publication year: | 2020 |
| Tag: | Diels-Alder reaction; furan-functionalised; melamine-formaldehyde; particle; thermoset |
| Volume: | 127 |
| Page Number: | 12 |
| First Page: | 1 |
| Last Page: | 12 |
| Article Number: | 109601 |
| DDC classes: | 660 Technische Chemie |
| Open access?: | Nein |
| Licence (German): |  In Copyright - Urheberrechtlich geschützt |
