Synthesis, structure, and frequency-doubling effect of calcium cyanurate
- Calcium cyanurate is synthesized by reacting calcium chloride with potassium cyanate following a solid-state reaction. The formation of the new compound Ca3(O3C3N3)2 (CCY), which occurs by the cyclotrimerization of cyanate ions, was examined thermoanalytically and the crystal structure was determined by single-crystal structure analysis. The structure of CCY is closely related to the structure of the well-known oxoborate β-BaB2O4 (BBO). Second harmonic generation (SHG) measurements on crystal powders show a higher SHG efficiency for CCY than for BBO by about one order of magnitude.
| Author of HS Reutlingen | Wackenhut, Frank |
|---|---|
| DOI: | https://doi.org/10.1002/anie.201407708 |
| ISSN: | 1433-7851 |
| Published in: | Angewandte Chemie : International edition |
| Publisher: | Wiley-VCH |
| Place of publication: | Weinheim |
| Document Type: | Journal article |
| Language: | English |
| Publication year: | 2014 |
| Volume: | 53 |
| Issue: | 51 |
| Page Number: | 4 |
| First Page: | 14260 |
| Last Page: | 14263 |
| DDC classes: | 540 Chemie |
| Open access?: | Nein |
| Licence (German): |  In Copyright - Urheberrechtlich geschützt |
