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Foam stabilized by fly ash nanoparticles for enhancing oil recovery

  • Foam has been employed as an improved or enhanced oil recovery method to overcome gravity override and the channeling and fingering of the injected gas, which arises because of the low density and viscosity of the injected fluid combined with the rock heterogeneity. A major challenge, however, is the stability of the generated foam when it contacts the oil. In this study we investigate the feasibility of using inexpensive nanoparticles made of coal fly ash, an abundantly available waste product of coal power plants, as a foam booster. We investigate the viability of reducing the size of fly ash particles to 100−200 nm using high-frequency ultrasonic grinding. We also study the foaminess (foamability), strength, and stability of the foams made with minor concentrations of fly ash nanoparticles and surfactant, both in bulk and porous media. The effect of monovalent and divalent ion concentration on the foaminess of the nanoash suspension combined with very low concentrations of a commercial alpha olefin sulfonate (AOS) surfactant, in the presence and absence of oil, is studied. We observe that bulk foam that contains very small amounts of nanoash particles shows a higher stability in the presence of model oils. Furthermore, experiments in porous media exhibit remarkably stronger foam with mixtures of nanoash and surfactant, such that the amount of produced liquids from the cores significantly increases. For the first time we show that nanoash can be used to stabilize nitrogen foam in the presence of crude oil at high temperature and pressure. In the presence of oil, the nanoash−AOS foam shows a higher stability, although crude oil tends to form stable emulsions in water in the presence of nanoash.

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Metadaten
Name:Krastev, Rumen
DOI:https://doi.org/10.1021/acs.iecr.5b03955
ISSN:0888-5885
eISSN:1520-5045
Erschienen in:Industrial & engineering chemistry research
Publisher:American Chemical Society
Place of publication:Columbus, Ohio
Document Type:Article
Language:English
Year of Publication:2015
Volume:54
Issue:50
Pagenumber:10
First Page:12482
Last Page:12491
Dewey Decimal Classification:540 Chemie
Open Access:Nein
Licence (English):License Logo  Lizenzbedingungen ACS