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This paper presents the first part of a research-work conducted at the University of Applied Sciences (HFT- Stuttgart). The aim of the research was to investigate the potential of low-cost renewable energy systems to reduce the energy demand of the building sector in hot and dry areas. Radiative cooling to the night sky represents a low-cost renewable energy source. The dry desert climate conditions promote radiative cooling applications. The system technology adopted in this work is based on uncovered solar thermal collectors integrated into the building’s hydronic system. By implementing different control strategies, the same system could be used for cooling as well as for heating applications. This paper focuses on identifying the collector parameters which are required as the coefficients to configure such an unglazed collector for calibrating its mathematical model within the simulation environment. The parameter identification process implies testing the collector for its thermal performance. This paper attempts to provide an insight into the dynamic testing of uncovered solar thermal collectors (absorbers), taking into account their prospective operation at nighttime for radiative cooling applications. In this study, the main parameters characterizing the performance of the absorbers for radiative cooling applications are identified and obtained from standardized testing protocol. For this aim, a number of plastic solar absorbers of different designs were tested on the outdoor test-stand facility at HFT-Stuttgart for the characterization of their thermal performance. The testing process was based on the quasi-dynamic test method of the international standard for solar thermal collectors EN ISO 9806. The test database was then used within a mathematical optimization tool (GenOpt) to determine the optimal parameter settings of each absorber under testing. Those performance parameters were significant to compare the thermal performance of the tested absorbers. The coefficients (identified parameters) were used then to plot the thermal efficiency curves of all absorbers, for both the heating and cooling modes of operation. Based on the intended main scope of the system utilization (heating or cooling), the tested absorbers could be benchmarked. Hence, one of those absorbers was selected to be used in the following simulation phase as was planned in the research-project.
During the first years of the last decade, Egypt used to face recurrent electricity cut-offs in summer. In the past few years, the electricity tariff dramatically increased. Radiative cooling to the clear night sky is a renewable energy source that represents a relative solution. The dry desert climate promotes nocturnal radiative cooling applications. This study investigates the potential of nocturnal radiative cooling systems (RCSs) to reduce the energy consumption of the residential building sector in Egypt. The system technology proposed in this work is based on uncovered solar thermal collectors integrated into the building hydronic system. By implementing different control strategies, the same system could be used for both cooling and heating applications. The goal of this paper is to analyze the performance of RCSs in residential buildings in Egypt. The dynamic simulation program TRNSYS was used to simulate the thermal behavior of the system. The relevant issues of Egypt as a case-study are firstly overviewed. Then the paper introduces the work done to develop a building model that represents a typical residential apartment in Egypt. Typical occupancy profiles were developed to define the internal thermal gains. The adopted control strategy to optimize the system operation is presented as well. To fully understand and hence evaluate the operation of the proposed RCS, four simulation cases were considered: 1. a reference case (fully passive), 2. the stand-alone operation of the RCS, 3. ideal heating & cooling operation (fully-active), and 4. the hybrid-operation (when the active cooling system is supported by the proposed RCS). The analysis considered the main three distinct climates in Egypt, represented by the cities of Alexandria, Cairo and Asyut. The hotter and drier weather conditions resulted in a higher cooling potential and larger temperature differences. The simulated cooling power in Asyut was 28.4 W/m² for a 70 m² absorber field. For a smaller field area of 10 m², the cooling power reached 109 W/m² but with humble temperature differences. To meet the rigorous thermal comfort conditions, the proposed sensible RCS cannot fully replace conventional air-conditioning units, especially in humid areas like Alexandria. When working in a hybrid system, a 10% reduction in the active cooling energy demand could be achieved in Asyut to keep the cooling set-point at 24 °C. This percentage reduction was nearly doubled when the thermal comfort set-point was increased by two degrees (26 °C). In a sensitivity analysis, external shading devices as a passive measure as well as the implementation of the Egyptian code for buildings (ECP306/1–2005) were also investigated. The analysis of this study raised other relevant aspects to discuss, e.g. system-sizing, environmental effects, limitations and recommendations.
As fuel prices climb and the global automotive sector migrates to more sustainable vehicle technologies, the future of South Africa’s minibus taxis is in flux. The authors’ previous research has found that battery electric technology struggles to meet all the mobility requirements of minibus taxis. They investigate the technical feasibility of powering taxis with hydrogen fuel cells instead. The following results are projected using a custom-built simulator, and tracking data of taxis based in Stellenbosch, South Africa. Each taxi requires around 12 kg of hydrogen gas per day to travel an average distance of 360 km. 465 kWh of electricity, or 860 m2 of solar panels, would electrolyse the required green hydrogen. An economic analysis was conducted on the capital and operational expenses of a system of ten hydrogen taxis and an electrolysis plant. Such a pilot project requires a minimum investment of € 3.8 million (R 75 million), for a 20 year period. Although such a small scale roll-out is technically feasible and would meet taxis’ performance requirements, the investment cost is too high, making it financially unfeasible. They conclude that a large scale solution would need to be investigated to improve financial feasibility; however, South Africa’s limited electrical generation capacity poses a threat to its technical feasibility. The simulator is uploaded at: https://gitlab.com/eputs/ev-fleet-sim-fcv-model.
Most Question-answering (QA) systems rely on training data to reach their optimal performance. However, acquiring training data for supervised systems is both time-consuming and resource-intensive. To address this, in this paper, we propose TFCSG, an unsupervised similar question retrieval approach that leverages pre-trained language models and multi-task learning. Firstly, topic keywords in question sentences are extracted sequentially based on a latent topic-filtering algorithm to construct unsupervised training corpus data. Then, the multi-task learning method is used to build the question retrieval model. There are three tasks designed. The first is a short sentence contrastive learning task. The second is the question sentence and its corresponding topic sequence similarity judgment task. The third is using question sentences to generate their corresponding topic sequence task. The three tasks are used to train the language model in parallel. Finally, similar questions are obtained by calculating the cosine similarity between sentence vectors. The comparison experiment on public question datasets that TFCSG outperforms the comparative unsupervised baseline method. And there is no need for manual marking, which greatly saves human resources.
UV hyperspectral imaging (225 nm–410 nm) was used to identify and quantify the honey- dew content of real cotton samples. Honeydew contamination causes losses of millions of dollars annually. This study presents the implementation and application of UV hyperspectral imaging as a non-destructive, high-resolution, and fast imaging modality. For this novel approach, a reference sample set, which consists of sugar and protein solutions that were adapted to honeydew, was set-up. In total, 21 samples with different amounts of added sugars/proteins were measured to calculate multivariate models at each pixel of a hyperspectral image to predict and classify the amount of sugar and honeydew. The principal component analysis models (PCA) enabled a general differentiation between different concentrations of sugar and honeydew. A partial least squares regression (PLS-R) model was built based on the cotton samples soaked in different sugar and protein concentrations. The result showed a reliable performance with R2cv = 0.80 and low RMSECV = 0.01 g for the valida- tion. The PLS-R reference model was able to predict the honeydew content laterally resolved in grams on real cotton samples for each pixel with light, strong, and very strong honeydew contaminations. Therefore, inline UV hyperspectral imaging combined with chemometric models can be an effective tool in the future for the quality control of industrial processing of cotton fibers.
Flame-retardant finishing of cotton fabrics using DOPO functionalized alkoxy- and amido alkoxysilane
(2023)
In the present study, DOPO-based alkoxysilane (DOPO-ETES) and amido alkoxysilane (DOPO-AmdPTES) were synthesized by one-step and without by-products as halogen-free flame retardants. The flame retardants were applied on cotton fabric utilizing sol–gel method and pad-dry-cure finishing process. The flame retardancy, the thermal stability and the combustion ehaviour of treated cotton were evaluated by surface and bottom edge ignition flame test (according to EN ISO 15025), thermogravimetric analysis (TGA) and micro-scale combustion calorimeter (MCC). Unlike CO/DOPO-ETES sample, cotton treated with DOPO-AmdPTES nanosols exhibits self-extinguishing ehaviour with high char residue, an improvement of the LOI value and a significant reduction of the PHRR, HRC and THR compared to pristine cotton. Cotton finished with DOPO-AmdPTES reveals a semi-durability after ten laundering cycles keeping the flame-retardant properties unchanged. According to the results obtained from TGA-FTIR, Py-GC/MS and XPS, the major activity of flame retardant occurs in the condensed phase via catalytic induced char formation as physical barrier along with the activity in the gas phase derived mainly from the dilution effect. The early degradation of CO/DOPO-AmdPTES compared to CO/DOPO-ETES, triggered by the cleavage of the weak bond between P and C=O, as the DFT study indicated, provides the beneficial effect of this flame retardant on the fire resistance of cellulose.
The chemical recycling of used motor oil via catalytic cracking to convert it into secondary diesel-like fuels is a sustainable and technically attractive solution for managing environmental concerns associated with traditional disposal. In this context, this study was conducted to screen basic and acidic-aluminum silicate catalysts doped with different metals, including Mg, Zn, Cu, and Ni. The catalysts were thoroughly characterized using various techniques such as N2 adsorption–desorption isotherms, FT-IR spectroscopy, and TG analysis. The liquid and gaseous products were identified using GC, and their characteristics were compared with acceptable ranges from ASTM characterization methods for diesel fuel. The results showed that metal doping improved the performance of the catalysts, resulting in higher conversion rates of up to 65%, compared to thermal (15%) and aluminum silicates (≈20%). Among all catalysts, basic aluminum silicates doped with Ni showed the best catalytic performance, with conversions and yields three times higher than aluminum silicate catalysts. These findings significantly contribute to developing efficient and eco-friendly processes for the chemical recycling of used motor oil. This study highlights the potential of basic aluminum silicates doped with Ni as a promising catalyst for catalytic cracking and encourages further research in this area.
Facing ever-looming climate change, studying the drivers for individuals' Information Systems (IS) Use to reduce environmental harm gains momentum. While extant research on the antecedents of sustainable IS Use has focused on specific theories, interventions, contexts, and technologies, a holistic understanding has become increasingly elusive, with a synthesis remaining absent. We employ a systematic literature review methodology to shed light on the driving antecedents for sustainable IS Use among individual consumers. Our results build on findings of 29 empirical studies drawn from 598 articles retrieved from our premier outlets and a forward/backward search. The analysis reveals six salient complementary antecedents: Relief, Empowerment, Default, User-centricity, Salience, and Encouragement. We recommend considering these concepts when developing, deploying, promoting, or regulating digital technologies to mitigate individual consumers' emissions. Along with memorable and implementable concepts, our theoretical framework offers a novel conceptualization and four promising avenues for researchers on sustainable IS Use.
The proliferation of smart technologies transforms the way individual consumers perform tasks. Considerable research alludes that smart technologies are often related to domestic energy consumption. However, it remains unclear how such technologies transform tasks and thereby impact our planet. We explore the role of technological smartness in personal day-to-day tasks that help create a more sustainable future. In the absence of theory, but facing extensive changes in everyday life enabled by smart technologies, we draw on phenomenon-based theorizing (PBT) guidelines. As anchor, we refer to task endogeneity related to task-technology fit theory (TTF). As infusion, we employ theory on public goods. Our model proposes novel relations between the concepts of smart autonomy and -transparency with sustainable task outcomes, mediated by task convenience and task significance. We discuss some implications, limitations, and future research opportunities.
The properties of polyelectrolyte multilayers are ruled by the process parameters employed during self-assembly. This is the first study in which a design of experiment approach was used to validate and control the production of ultrathin polyelectrolyte multilayer coatings by identifying the ranges of critical process parameters (polyelectrolyte concentration, ionic strength and pH) within which coatings with reproducible properties (thickness, refractive index and hydrophilicity) are created. Mathematical models describing the combined impact of key process parameters on coatings properties were developed demonstrating that only ionic strength and pH affect the coatings thickness, but not polyelectrolyte concentration. While the electrolyte concentration had a linear effect, the pH contribution was described by a quadratic polynomial. A significant contribution of this study is the development of a new approach to estimate the thickness of polyelectrolyte multilayer nanofilms by quantitative rhodamine B staining, which might be useful in all cases when ellipsometry is not feasible due to the shape complexity or small size of the coated substrate. The novel approach proposed here overcomes the limitations of known methods as it offers a low spatial sampling size and the ability to analyse a wide area without restrictions on the chemical composition and shape of the substrate.