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Melamine Formaldehyde (MF) resins are thermosetting synthetic materials. The present work deals with the evaluation of the impregnation process, modification of resin structure and abrasion resistant applications. During the industrial process paper is impregnated by aqueous oligomers. The drying procedure and the corresponding residual volatile content is a crucial step during production, because of its influence on the later surface quality. Standard measurement routines do not differentiate between physical and chemical origin. Using TGA and DSC methods, the evaporation of water could be characterized as a clear separation of solvent evaporation and the release of water during condensation. The method could be used to upgrade current quality control as well as reaction condition tuning. According to the characteristics of duroplastic material, the formed network is very dense but also brittle. Challenging applications require highly modified resins in order to decrease the network density. Substances from bio renewable resources offer chemical possibilities for covalent crosslinking. Several substance classes have been tested for compatibility via hydroxyl groups or amines. The addition of polyols under appropriate reaction conditions showed chemical incorporation into the MF prepolymer. NMR methods have been used to characterize the resins. The synthesized polymers represent a suitable alternative for the usage in challenging furniture and flooring laminate applications. MF applications for scratch and wear resistant surfaces are commonly reinforced by multiple layer setups with inorganic particles. Fulfilling normative requirements a one sheet setup of decorative paper has been developed and tested. The incorporation of special corundum particles directly on the decorative printed paper combined with a new coating system resulted in surfaces of the requested quality for wear resistance surfaces.
Compared to diesel or gasoline, using compressed natural gas as a fuel allows for significantly decreased carbon dioxide emissions. With the benefits of this technology fully exploited, substantial increases of engine efficiency can be expected in the near future. However, this will lead to exhaust gas temperatures well below the range required for the catalytic removal of residual methane, which is a strong greenhouse gas. By combination with a countercurrent heat exchanger, the temperature level of the catalyst can be raised significantly in order to achieve sufficient levels of methane conversion with minimal additional fuel penalty. This thesis provides fundamental theoretical background of these so-called heat-integrated exhaust purification systems. On this basis, prototype heat exchangers and appropriate operating strategies for highly dynamic operation in passenger cars are developed and evaluated.