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Gegenstand dieser Arbeit ist die Darstellung und Charakterisierung einheitlicher, mesoporöser Silica-Partikel (MPSM) im Mikrometerbereich mit maßgeschneiderten Partikel- und Porendesign für die Hochleistungsflüssigkeitschromatographie. Die Synthese umfasst die Einlagerung von Silica-Nanopartikeln (SNP) in poröse organische Template, welche anschließend bei 600°C zersetzt werden. Die Impfsuspensionspolymerisation von Polystyrol-Partikeln, unter Verwendung von Glycidylmethacrylat, Ethylenglycoldimethacrylat und Porogenen, ermöglicht die Herstellung hochgradig einheitlicher, poröser p(GMA-co-EDMA)-Template. Der Einfluss wesentlicher Faktoren, einschließlich des Monomer-Porogen-Verhältnisses, des Monomerverhältnisses und der Porogenzusammensetzung, werden systematisch untersucht sowie ihre Auswirkungen auf die Porengröße, das Porenvolumen und die spezifische Oberfläche erläutert. Die Anbindung aminofunktionalisierter Substanzen erfolgt durch die Ringöffnung der Epoxidgruppe. Im anschließenden basischen Sol-Gel-Prozess werden die Silica-Nanopartikel aufgrund der Ladungsunterschiede in die funktionalisierten p(GMA-co-EDMA)-Template eingebaut. Die Partikelgröße der SNP beeinflusst wesentlich die Poreneigenschaften der MPSM und hängt von drei Faktoren ab: (i) der Wachstumsgeschwindigkeit in der kontinuierlichen Phase, die durch die Einstellungen des Sol-Gel-Prozesses gesteuert wird, (ii) der Diffusionsrate, die durch elektrostatische Anziehung reguliert wird und vom Grad der Funktionalisierung abhängt und (iii) der Porosität des Polymer-Templats. Die gezielte Anpassung der Poreneigenschaften durch die Prozesseinstellungen erlaubt die präzise Herstellung von MPSM, die auf spezifische Trennherausforderungen zugeschnitten werden und somit die Qualität der HPLC verbessern. Die vorgestellte Synthesestrategie ermöglicht, aufgrund des stufenweisen molekularen Aufbaus, eine bessere Adaption der stationären Phase an spezifische Trennherausforderungen.
After more than three decades of electronic design automation, most layouts for analog integrated circuits are still handcrafted in a laborious manual fashion today. This book presents Self-organized Wiring and Arrangement of Responsive Modules (SWARM), a novel interdisciplinary methodology addressing the design problem with a decentralized multi-agent system. Its basic approach, similar to the roundup of a sheep herd, is to let autonomous layout modules interact with each other inside a successively tightened layout zone. Considering various principles of self-organization, remarkable overall solutions can result from the individual, local, selfish actions of the modules. Displaying this fascinating phenomenon of emergence, examples demonstrate SWARM’s suitability for floorplanning purposes and its application to practical place-and-route problems. From an academic point of view, SWARM combines the strengths of procedural generators with the assets of optimization algorithms, thus paving the way for a new automation paradigm called bottom-up meets top-down.
Product-Service Systems (PSS) in the fashion industry : an analysis of intra-organizational factors
(2018)
The fashion industry is a vast industry that has grown tremendously over the last decades. This growth causes significant environmental impact since the production of clothes involves high input of energy, water, chemicals and generates great volumes of waste. Even though fashion firms have started to address this challenge by adopting environmental standards, it has turned out that the sole use of eco-friendly material and new manufacturing techniques is insufficient. Instead, sustainable business models are increasingly gaining attention to solve the environmental problems. Offers to rent, swap, repair or redesign clothes are among the most prominent and promising examples. For analytical purposes, these concepts can be assigned to the growing research stream of Product-Service Systems (PSS) that shift the focus from the pure sale of a product toward complementary or substitutional service offers. This decouples customer satisfaction from material consumption, prolongs the garments' lifetime and thus diminishes both material input and appertaining waste. Besides environmental sustainability, PSS imply potential economic benefits for organizations. Particularly in highly competitive industries like the fashion industry, PSS allow firms to differentiate, better compete with cost pressure and mitigate the risk of being imitated by rivels since service is more difficult to replicate. However, fashion PSS are still mainly operated in a niche market by small firms and have yet to be anchored in the mainstream fashion industry.
After more than three decades of electronic design automation, most layouts for analog integrated circuits are still handcrafted in a laborious manual fashion today. Obverse to the highly automated synthesis tools in the digital domain (coping with the quantitative difficulty of packing more and more components onto a single chip – a desire well known as More Moore), analog layout automation struggles with the many diverse and heavily correlated functional requirements that turn the analog design problem into a More than Moore challenge. Facing this qualitative complexity, seasoned layout engineers rely on their comprehensive expert knowledge to consider all design constraints that uncompromisingly need to be satisfied. This usually involves both formally specified and nonformally communicated pieces of expert knowledge, which entails an explicit and implicit consideration of design constraints, respectively.
Existing automation approaches can be basically divided into optimization algorithms (where constraint consideration occurs explicitly) and procedural generators (where constraints can only be taken into account implicitly). As investigated in this thesis, these two automation strategies follow two fundamentally different paradigms denoted as top-down automation and bottom-up automation. The major trait of top-down automation is that it requires a thorough formalization of the problem to enable a self-intelligent solution finding, whereas a bottom-up automatism –controlled by parameters– merely reproduces solutions that have been preconceived by a layout expert in advance. Since the strengths of one paradigm may compensate the weaknesses of the other, it is assumed that a combination of both paradigms –called bottom-up meets top-down– has much more potential to tackle the analog design problem in its entirety than either optimization-based or generator-based approaches alone.
Against this background, the thesis at hand presents Self-organized Wiring and Arrangement of Responsive Modules (SWARM), an interdisciplinary methodology addressing the design problem with a decentralized multi-agent system. Its basic principle, similar to the roundup of a sheep herd, is to let responsive mobile layout modules (implemented as context-aware procedural generators) interact with each other inside a user-defined layout zone. Each module is allowed to autonomously move, rotate and deform itself, while a supervising control organ successively tightens the layout zone to steer the interaction towards increasingly compact (and constraint compliant) layout arrangements. Considering various principles of self-organization and incorporating ideas from existing decentralized systems, SWARM is able to evoke the phenomenon of emergence: although each module only has a limited viewpoint and selfishly pursues its personal objectives, remarkable overall solutions can emerge on the global scale.
Several examples exhibit this emergent behavior in SWARM, and it is particularly interesting that even optimal solutions can arise from the module interaction. Further examples demonstrate SWARM’s suitability for floorplanning purposes and its application to practical place-and-route problems. The latter illustrates how the interacting modules take care of their respective design requirements implicitly (i.e., bottom-up) while simultaneously paying respect to high level constraints (such as the layout outline imposed top-down by the supervising control organ). Experimental results show that SWARM can outperform optimization algorithms and procedural generators both in terms of layout quality and design productivity. From an academic point of view, SWARM’s grand achievement is to tap fertile virgin soil for future works on novel bottom-up meets top-down automatisms. These may one day be the key to close the automation gap in analog layout design.
Service robots need to be aware of persons in their vicinity in order to interact with them. People tracking enables the robot to perceive persons by fusing the information of several sensors. Most robots rely on laser range scanners and RGB cameras for this task. The thesis focuses on the detection and tracking of heads. This allows the robot to establish eye contact, which makes interactions feel more natural.
Developing a fast and reliable pose invariant head detector is challenging. The head detector that is proposed in this thesis works well on frontal heads, but is not fully pose-invariant. This thesis further explores adaptive tracking to keep track of heads that do not face the robot. Finally, head detector and adaptive tracker are combined within a new people tracking framework and experiments show its effectiveness compared to a state-of the-art system.
Este trabajo se enmarca dentro del vasto contexto de Ciudades Inteligentes, y se centra en el área de la conducción inteligente de vehículos, tanto en zonas urbanas como interurbanas, mediante la recogida de datos en tiempo real, medidos con sensores, por parte de los propios conductores, así como de datos capturados mediante simulación.
El objetivo de este trabajo es doble. Por un lado, el estudio y aplicación de las diferentes técnicas y métodos de detección de valores atípicos en bases de datos multivariantes, además de una comparativa entre ellos mediante las pruebas llevadas a cabo con datos de tráfico real. Y por otro lado, establecer una relación entre las situaciones anómalas de tráfico, como puedan ser atascos o accidentes, con los valores atípicos multivariantes encontrados.
La detección de valores atípicos representa una de las tareas más importantes a la hora de realizar cualquier análisis de datos, sea cual sea el dominio o área de estudio, ya que entre sus funciones primordiales se encuentra el descubrir información útil, que resulta de gran valor, y que por lo general queda oculta por la alta dimensión de los datos.
Con el uso de mecanismos de detección de valores atípicos junto con métodos de clasificación supervisada, se va a poder llevar a cabo el reconocimiento de elementos de la infraestructura vial urbana como pueden ser rotondas, pasos de cebra, cruces o semáforos.
Anhand von drei empirischen Studien zeigt Christina Kühnl, wie Unternehmen ihren Innovationsprozess optimieren bzw. wie sie die Adoption einer Innovation in ihrer Organisation sicherstellen können. Dabei vergleicht sie die Erfolgsfaktoren von Produkt- und Dienstleistungsinnovationen unter Berücksichtigung nichtlinearer Effekte, identifiziert unternehmensinterne Erfolgsfaktoren und verdeutlicht, welchen Einfluss das soziale Umfeld auf die individuelle Adoptionsentscheidung ausübt.
In dieser Arbeit wird ein Ansatz zur Unterstützung von Werkern, Meistern und Instandhaltern vorgestellt, der es ermöglicht, aus der auftretenden Situation heraus (ad hoc), auf aktuelle notwendige Informationen und die Zusammenhänge in einer variantenreichen Serienfertigung zuzugreifen. Schwerpunkt bildet das unternehmensneutrale Gesamtkonzept des fertigungsnahen Kontextinformationssystems, das aus dem Produktionsumgebungsmodell und der Systemarchitektur besteht. Das Produktionsumgebungsmodell beschreibt und vernetzt enthaltene Informationen und Zusammenhänge einer variantenreichen Serienfertigung. Hauptordnungskriterien sind hier die Zugehörigkeit zu einer bestimmten Gruppe (Typ), die Identität eines Gegenstands, dessen Ort und Betriebszustand über die Zeit. Die Systemarchitektur ist modular aufgebaut. Die Module werden in Erfassungsmodule, Kontextverwaltungsmodule, Funktionsmodule zur automatischen und manuellen Informationsfilterung sowie Präsentationsmodule untergliedert und kommunizieren über eine einheitliche Schnittstelle.