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This paper presents the first part of a research-work conducted at the University of Applied Sciences (HFT- Stuttgart). The aim of the research was to investigate the potential of low-cost renewable energy systems to reduce the energy demand of the building sector in hot and dry areas. Radiative cooling to the night sky represents a low-cost renewable energy source. The dry desert climate conditions promote radiative cooling applications. The system technology adopted in this work is based on uncovered solar thermal collectors integrated into the building’s hydronic system. By implementing different control strategies, the same system could be used for cooling as well as for heating applications. This paper focuses on identifying the collector parameters which are required as the coefficients to configure such an unglazed collector for calibrating its mathematical model within the simulation environment. The parameter identification process implies testing the collector for its thermal performance. This paper attempts to provide an insight into the dynamic testing of uncovered solar thermal collectors (absorbers), taking into account their prospective operation at nighttime for radiative cooling applications. In this study, the main parameters characterizing the performance of the absorbers for radiative cooling applications are identified and obtained from standardized testing protocol. For this aim, a number of plastic solar absorbers of different designs were tested on the outdoor test-stand facility at HFT-Stuttgart for the characterization of their thermal performance. The testing process was based on the quasi-dynamic test method of the international standard for solar thermal collectors EN ISO 9806. The test database was then used within a mathematical optimization tool (GenOpt) to determine the optimal parameter settings of each absorber under testing. Those performance parameters were significant to compare the thermal performance of the tested absorbers. The coefficients (identified parameters) were used then to plot the thermal efficiency curves of all absorbers, for both the heating and cooling modes of operation. Based on the intended main scope of the system utilization (heating or cooling), the tested absorbers could be benchmarked. Hence, one of those absorbers was selected to be used in the following simulation phase as was planned in the research-project.
During the first years of the last decade, Egypt used to face recurrent electricity cut-offs in summer. In the past few years, the electricity tariff dramatically increased. Radiative cooling to the clear night sky is a renewable energy source that represents a relative solution. The dry desert climate promotes nocturnal radiative cooling applications. This study investigates the potential of nocturnal radiative cooling systems (RCSs) to reduce the energy consumption of the residential building sector in Egypt. The system technology proposed in this work is based on uncovered solar thermal collectors integrated into the building hydronic system. By implementing different control strategies, the same system could be used for both cooling and heating applications. The goal of this paper is to analyze the performance of RCSs in residential buildings in Egypt. The dynamic simulation program TRNSYS was used to simulate the thermal behavior of the system. The relevant issues of Egypt as a case-study are firstly overviewed. Then the paper introduces the work done to develop a building model that represents a typical residential apartment in Egypt. Typical occupancy profiles were developed to define the internal thermal gains. The adopted control strategy to optimize the system operation is presented as well. To fully understand and hence evaluate the operation of the proposed RCS, four simulation cases were considered: 1. a reference case (fully passive), 2. the stand-alone operation of the RCS, 3. ideal heating & cooling operation (fully-active), and 4. the hybrid-operation (when the active cooling system is supported by the proposed RCS). The analysis considered the main three distinct climates in Egypt, represented by the cities of Alexandria, Cairo and Asyut. The hotter and drier weather conditions resulted in a higher cooling potential and larger temperature differences. The simulated cooling power in Asyut was 28.4 W/m² for a 70 m² absorber field. For a smaller field area of 10 m², the cooling power reached 109 W/m² but with humble temperature differences. To meet the rigorous thermal comfort conditions, the proposed sensible RCS cannot fully replace conventional air-conditioning units, especially in humid areas like Alexandria. When working in a hybrid system, a 10% reduction in the active cooling energy demand could be achieved in Asyut to keep the cooling set-point at 24 °C. This percentage reduction was nearly doubled when the thermal comfort set-point was increased by two degrees (26 °C). In a sensitivity analysis, external shading devices as a passive measure as well as the implementation of the Egyptian code for buildings (ECP306/1–2005) were also investigated. The analysis of this study raised other relevant aspects to discuss, e.g. system-sizing, environmental effects, limitations and recommendations.
Learning factories present a promising environment for education, training and research, especially in manufacturing related areas which are a main driver for wealth creation in any nation. While numerous learning factories have been built in industry and academia in the last decades, a comprehensive scientific overview of the topic is still missing. This paper intends to close this gap establishing the state of the art of learning factories. The motivations, historic background, and the didactic foundations of learning factories are outlined. Definitions of the term learning factory and the corresponding morphological model are provided. An overview of existing learning factory approaches in industry and academia is provided, showing the broad range of different applications and varying contents. The state of the art of learning factories curricula design and their use to enhance learning and research as well as potentials and limitations are presented. Conclusions and an outlook on further research priorities are offered.
In the last decade, numerous learning factories for education, training, and research have been built up in industry and academia. In recent years learning factory initiatives were elevated from a local to a European and then to a worldwide level. In 2014 the CIRP Collaborative Working Group (CWG) on Learning Factories enables a lively exchange on the topic "Learning Factories for future oriented research and education in manufacturing". In this paper results of discussions inside the CWG are presented. First, what is meant by the term Learning Factory is outlined. Second, based on the definition a description model (morphology) for learning factories is presented. The morphology covers the most relevant characteristics and features of learning factories in seven dimensions. Third, following the morphology the actual variance of learning factory manifestations is shown in six learning factory application scenarios from industrial training over education to research. Finally, future prospects of the learning factory concept are presented.
The physicochemical properties of synthetically produced bone substitute materials (BSM) have a major impact on biocompatibility. This affects bony tissue integration, osteoconduction, as well as the degradation pattern and the correlated inflammatory tissue responses including macrophages and multinucleated giant cells (MNGCs). Thus, influencing factors such as size, special surface morphologies, porosity, and interconnectivity have been the subject of extensive research. In the present publication, the influence of the granule size of three identically manufactured bone substitute granules based on the technology of hydroxyapatite (HA)-forming calcium phosphate cements were investigated, which includes the inflammatory response in the surrounding tissue and especially the induction of MNGCs (as a parameter of the material degradation). For the in vivo study, granules of three different size ranges (small = 0.355–0.5 mm; medium = 0.5–1 mm; big = 1–2 mm) were implanted in the subcutaneous connective tissue of 45 male BALB/c mice. At 10, 30, and 60 days post implantationem, the materials were explanted and histologically processed. The defect areas were initially examined histopathologically. Furthermore, pro- and anti-inflammatory macrophages were quantified histomorphometrically after their immunohistochemical detection. The number of MNGCs was quantified as well using a histomorphometrical approach. The results showed a granule size-dependent integration behavior. The surrounding granulation tissue has passivated in the groups of the two bigger granules at 60 days post implantationem including a fibrotic encapsulation, while a granulation tissue was still present in the group of the small granules indicating an ongoing cell-based degradation process. The histomorphometrical analysis showed that the number of proinflammatory macrophages was significantly increased in the small granules at 60 days post implantationem. Similarly, a significant increase of MNGCs was detected in this group at 30 and 60 days post implantationem. Based on these data, it can be concluded that the integration and/or degradation behavior of synthetic bone substitutes can be influenced by granule size.
As fuel prices climb and the global automotive sector migrates to more sustainable vehicle technologies, the future of South Africa’s minibus taxis is in flux. The authors’ previous research has found that battery electric technology struggles to meet all the mobility requirements of minibus taxis. They investigate the technical feasibility of powering taxis with hydrogen fuel cells instead. The following results are projected using a custom-built simulator, and tracking data of taxis based in Stellenbosch, South Africa. Each taxi requires around 12 kg of hydrogen gas per day to travel an average distance of 360 km. 465 kWh of electricity, or 860 m2 of solar panels, would electrolyse the required green hydrogen. An economic analysis was conducted on the capital and operational expenses of a system of ten hydrogen taxis and an electrolysis plant. Such a pilot project requires a minimum investment of € 3.8 million (R 75 million), for a 20 year period. Although such a small scale roll-out is technically feasible and would meet taxis’ performance requirements, the investment cost is too high, making it financially unfeasible. They conclude that a large scale solution would need to be investigated to improve financial feasibility; however, South Africa’s limited electrical generation capacity poses a threat to its technical feasibility. The simulator is uploaded at: https://gitlab.com/eputs/ev-fleet-sim-fcv-model.
With the expansion of cyber-physical systems (CPSs) across critical and regulated industries, systems must be continuously updated to remain resilient. At the same time, they should be extremely secure and safe to operate and use. The DevOps approach caters to business demands of more speed and smartness in production, but it is extremely challenging to implement DevOps due to the complexity of critical CPSs and requirements from regulatory authorities. In this study, expert opinions from 33 European companies expose the gap in the current state of practice on DevOps-oriented continuous development and maintenance. The study contributes to research and practice by identifying a set of needs. Subsequently, the authors propose a novel approach called Secure DevOps and provide several avenues for further research and development in this area. The study shows that, because security is a cross-cutting property in complex CPSs, its proficient management requires system-wide competencies and capabilities across the CPSs development and operation.
Der betriebswirtschaftlichen Forschung in der Textil- und Bekleidungsindustrie gelingt es nicht, Lösungen zu erarbeiten, die das Nachhaltigkeitsproblem der Branche lösen. Dies liegt primär an der Art und Weise, wie in unserem Fachbereich geforscht wird. In Anbetracht der Problemstellung kann der starke Fokus auf empirische Arbeiten nur eine begrenzte Hilfestellung leisten. Denn empirische Forschung erfolgt innerhalb der bestehenden Denkmuster und ist tendenziell gegenwarts- oder vergangenheitsorientiert. Für die Lösung zukunftsorientierter Fragestellungen werden jedoch völlig neue Parameter und Logiken benötigt. Ein Umdenken ist gefragt.
Implementation of product-service systems (PSS) requires structural changes in the way that business in manufacturing industries is traditionally conducted. Literature frequently mentions the importance of human resource management (HRM), since people are involved in the entire process of PSS development and employees are the primary link to customers. However, to this day, no study has provided empirical evidence whether and in what way HRM of firms that implement PSS differs from HRM of firms that solely run a traditional manufacturing based business model. The aim of this study is to contribute to closing this gap by investigating the particular HR components of manufacturing firms that implement PSS and compare it with the HRM of firms that do not. The context of this study is the fashion industry, which is an ideal setting since it is a mature and highly competitive industry that is well-documented for causing significant environmental impact. PSS present a promising opportunity for fashion firms to differentiate and mitigate the industry’s ecological footprint. Analysis of variance (ANOVA) was conducted to analyze data of 102 international fashion firms. Findings reveal a significant higher focus on nearly the entire spectrum of HRM components of firms that implement PSS compared with firms that do not. Empirical findings and their interpretation are utilized to propose a general framework of the role of HRM for PSS implementation. This serves as a departure point for both scholars and practitioners for further research, and fosters the understanding of the role of HRM for managing PSS implementation.
Jeder weiß, dass die Textil- und Bekleidungsindustrie ein Nachhaltigkeitsproblem hat und es neuer Lösungsansätze bedarf. Auch Konsumenten und deren Verhalten haben einen entscheidenden Einfluss auf die Erfolgsaussichten einer nachhaltigen Entwicklung. Welche Rolle und Bedeutung obliegt jedoch dem einzelnen Mitarbeiter in diesem Prozess? Und welche Handlungsmaßnahmen können daraus abgeleitet werden? Eine empirische Analyse von über 100 internationalen Bekleidungsunternehmen gibt Aufschluss.
Product-Service Systems (PSS) in the fashion industry : an analysis of intra-organizational factors
(2018)
The fashion industry is a vast industry that has grown tremendously over the last decades. This growth causes significant environmental impact since the production of clothes involves high input of energy, water, chemicals and generates great volumes of waste. Even though fashion firms have started to address this challenge by adopting environmental standards, it has turned out that the sole use of eco-friendly material and new manufacturing techniques is insufficient. Instead, sustainable business models are increasingly gaining attention to solve the environmental problems. Offers to rent, swap, repair or redesign clothes are among the most prominent and promising examples. For analytical purposes, these concepts can be assigned to the growing research stream of Product-Service Systems (PSS) that shift the focus from the pure sale of a product toward complementary or substitutional service offers. This decouples customer satisfaction from material consumption, prolongs the garments' lifetime and thus diminishes both material input and appertaining waste. Besides environmental sustainability, PSS imply potential economic benefits for organizations. Particularly in highly competitive industries like the fashion industry, PSS allow firms to differentiate, better compete with cost pressure and mitigate the risk of being imitated by rivels since service is more difficult to replicate. However, fashion PSS are still mainly operated in a niche market by small firms and have yet to be anchored in the mainstream fashion industry.
The fashion industry is well documented for causing significant environmental impact. Product-service systems (PSS) present a promising way to solve this challenge. PSS shift the focus toward complementary service offers, which decouples customer satisfaction from material consumption and entails dematerialization. However, PSS are not ecoefficient by nature but need to be accompanied by corporate environmental management (CEM) practices. The objective of this article is to examine the potential of PSS to contribute to the environmental sustainability of today's fashion industry by investigating if fashion firms with a positive attitude toward PSS implementation also pursue goals related to the ecological environment. For this purpose, analysis of variance (ANOVA) is conducted to analyze data of 102 fashion firms. Results reveal that the diffusion of PSS in today's fashion industry is low and few firms consider implementing PSS. Results, furthermore, demonstrate that PSS implementation is positively related to CEM. This indicates that existing structures of CEM favor PSS implementation and unlock the eco-efficient potential of implemented PSS in the fashion industry.
In recent years the share economy has gained widespread success across different industries. Since small firms and new ventures obtain fewer resources, an increased focus on service allows them to differentiate and compete with cost pressure in traditionally manufacturing based industries. There still is a lack of understanding how these firms manage to successfully shift towards service-oriented business models. This paper adopts a dynamic capabilities approach to examine the particular microfoundations that underlie sensing, seizing and reconfiguring dynamic capabilities of early-stage service firms within a traditional retail market. The context of this study is the fashion industry. It is an ideal setting since it is characterized by severe competition, short life cycles, strong cost pressure and high volatility. There are few but increasing examples of entrepreneurial initiatives that try to compete by providing offers to resell, rent or swap clothes. Qualitative data of five early stage fashion ventures is analyzed. Findings reveal that the ability to develop and maintain long-term relationships is essential. It has also been found crucial to acquire knowledge from external network partners, delegate tasks and share information. Furthermore, skills for interacting with customers and adopting consumer feedback are critical. This study provides empirical evidence of dynamic capabilities of early-stage firms and contributes to knowledge on the factors that facilitate servitization in traditionally manufacturing based industries. For practitioners, the presented microfoundations provide a framework of critical tasks that allow them to develop and maintain a service oriented business model.
Venture capital and the innovative power of a state : econometric study including Google data
(2015)
This article focuses on venture capital investments and the innovative power of a state defined by its public infrastructure. The economic implications are evaluated by estimating several panel regression models. The novelty is twofold: on the one hand the research approach and on the other hand the new data set. The data ranges from 1995 to 2014 and consists of 10 European countries plus the US and Canada. For the first time we include Google search data on Venture Capital. The results show a significant increase in Venture Capital is mainly determined by economic conditions such as real GDP growth. The impact of the innovative power of a state is not significant. We find that Google data is positively related and significant in respect to Venture Capital investments too. Consequently, we confirm that private business investments cannot be created by government policy alone rather via solid macroeconomic conditions.
This study is about estimating the reproducibility of finding palpation points of three different anatomical landmarks in the human body (Xiphoid Process and the 2 Hip Crests) to support a navigated ultrasound application. On 6 test subjects with different body mass index the three palpation points were located five times by two examiners. The deviation from the target position was calculated and correlated to the fat thickness above each palpation point. The reproducibility of the measurements had a mean error of ≈13.5 mm +- 4 mm, which seems to be sufficient for the desired application field.
User innovators follow multiple diffusion and adoption pathways for their self-developed innovations. Users may choose to commercialize their self-developed products on the marketplace by becoming entrepreneurs. Few studies exist that focus on understanding personal and interpersonal factors that affect some user innovators’ entrepreneurial decision-making. Hence, this paper focuses on how user innovators make key decisions relating to opportunity recognition and evaluation and when opportunity evaluation leads to subsequent entrepreneurial action in the entrepreneurial process. We conducted an exploratory study using a multi-grounded theory methodology as the user entrepreneurship phenomenon embodies complex social processes. We collected data through the netnography approach that targeted 18 entrepreneurs with potentially relevant differences through crowdfunding platforms. We integrated self-determination, human capital, and social capital theory to address the phenomena under study. This study’s significant findings posit that users’ motives are dissatisfaction with existing goods, interest in innovation, altruism, social recognition, desire for independence, and economic benefits. Besides, use-related experience, product-related knowledge, product diffusion, and iterative feedback positively impact innovative users’ entrepreneurial decision-making.
Most Question-answering (QA) systems rely on training data to reach their optimal performance. However, acquiring training data for supervised systems is both time-consuming and resource-intensive. To address this, in this paper, we propose TFCSG, an unsupervised similar question retrieval approach that leverages pre-trained language models and multi-task learning. Firstly, topic keywords in question sentences are extracted sequentially based on a latent topic-filtering algorithm to construct unsupervised training corpus data. Then, the multi-task learning method is used to build the question retrieval model. There are three tasks designed. The first is a short sentence contrastive learning task. The second is the question sentence and its corresponding topic sequence similarity judgment task. The third is using question sentences to generate their corresponding topic sequence task. The three tasks are used to train the language model in parallel. Finally, similar questions are obtained by calculating the cosine similarity between sentence vectors. The comparison experiment on public question datasets that TFCSG outperforms the comparative unsupervised baseline method. And there is no need for manual marking, which greatly saves human resources.
Different types of raw cotton were investigated by a commercial ultraviolet-visible/near infrared (UV-Vis/NIR) spectrometer (210–2200 nm) as well as on a home-built setup for NIR hyperspectral imaging (NIR-HSI) in the range 1100–2200 nm. UV-Vis/NIR reflection spectroscopy reveals the dominant role proteins, hydrocarbons and hydroxyl groups play in the structure of cotton. NIR-HSI shows a similar result. Experimentally obtained data in combination with principal component analysis (PCA) provides a general differentiation of different cotton types. For UV-Vis/NIR spectroscopy, the first two principal components (PC) represent 82 % and 78 % of the total data variance for the UV-Vis and NIR regions, respectively. Whereas, for NIR-HSI, due to the large amount of data acquired, two methodologies for data processing were applied in low and high lateral resolution. In the first method, the average of the spectra from one sample was calculated and in the second method the spectra of each pixel were used. Both methods are able to explain ≥90 % of total variance by the first two PCs. The results show that it is possible to distinguish between different cotton types based on a few selected wavelength ranges. The combination of HSI and multivariate data analysis has a strong potential in industrial applications due to its short acquisition time and low-cost development. This study opens a novel possibility for a further development of this technique towards real large-scale processes.
Hyperspectral imaging and reflectance spectroscopy in the range from 200–380 nm were used to rapidly detect and characterize copper oxidation states and their layer thicknesses on direct bonded copper in a non-destructive way. Single-point UV reflectance spectroscopy, as a well-established method, was utilized to compare the quality of the hyperspectral imaging results. For the laterally resolved measurements of the copper surfaces an UV hyperspectral imaging setup based on a pushbroom imager was used. Six different types of direct bonded copper were studied. Each type had a different oxide layer thickness and was analyzed by depth profiling using X-ray photoelectron spectroscopy. In total, 28 samples were measured to develop multivariate models to characterize and predict the oxide layer thicknesses. The principal component analysis models (PCA) enabled a general differentiation between the sample types on the first two PCs with 100.0% and 96% explained variance for UV spectroscopy and hyperspectral imaging, respectively. Partial least squares regression (PLS-R) models showed reliable performance with R2c = 0.94 and 0.94 and RMSEC = 1.64 nm and 1.76 nm, respectively. The developed in-line prototype system combined with multivariate data modeling shows high potential for further development of this technique towards real large-scale processes.
UV hyperspectral imaging (225 nm–410 nm) was used to identify and quantify the honey- dew content of real cotton samples. Honeydew contamination causes losses of millions of dollars annually. This study presents the implementation and application of UV hyperspectral imaging as a non-destructive, high-resolution, and fast imaging modality. For this novel approach, a reference sample set, which consists of sugar and protein solutions that were adapted to honeydew, was set-up. In total, 21 samples with different amounts of added sugars/proteins were measured to calculate multivariate models at each pixel of a hyperspectral image to predict and classify the amount of sugar and honeydew. The principal component analysis models (PCA) enabled a general differentiation between different concentrations of sugar and honeydew. A partial least squares regression (PLS-R) model was built based on the cotton samples soaked in different sugar and protein concentrations. The result showed a reliable performance with R2cv = 0.80 and low RMSECV = 0.01 g for the valida- tion. The PLS-R reference model was able to predict the honeydew content laterally resolved in grams on real cotton samples for each pixel with light, strong, and very strong honeydew contaminations. Therefore, inline UV hyperspectral imaging combined with chemometric models can be an effective tool in the future for the quality control of industrial processing of cotton fibers.
Due to its wide-ranging endocrine functions, adipose tissue influences the whole body’s metabolism. Engineering long-term stable and functional human adipose tissue is still challenging due to the limited availability of suitable biomaterials and adequate cell maturation. We used gellan gum (GG) to create manual and bioprinted adipose tissue models because of its similarities to the native extracellular matrix and its easily tunable properties. Gellan gum itself was neither toxic nor monocyte activating. The resulting hydrogels exhibited suitable viscoelastic properties for soft tissues and were stable for 98 days in vitro. Encapsulated human primary adipose-derived stem cells (ASCs) were adipogenically differentiated for 14 days and matured for an additional 84 days. Live-dead staining showed that encapsulated cells stayed viable until day 98, while intracellular lipid staining showed an increase over time and a differentiation rate of 76% between days 28 and 56. After 4 weeks of culture, adipocytes had a univacuolar morphology, expressed perilipin A, and secreted up to 73% more leptin. After bioprinting establishment, we demonstrated that the cells in printed hydrogels had high cell viability and exhibited an adipogenic phenotype and function. In summary, GG-based adipose tissue models show long-term stability and allow ASCs maturation into functional, univacuolar adipocytes.
Adipose tissue is related to the development and manifestation of multiple diseases, demonstrating the importance of suitable in vitro models for research purposes. In this study, adipose tissue lobuli were explanted, cultured, and used as an adipose tissue control to evaluate in vitro generated adipose tissue models. During culture, lobule exhibited a stable weight, lactate dehydrogenase, and glycerol release over 15 days. For building up in vitro adipose tissue models, we adapted the biomaterial gelatin methacryloyl (GelMA) composition and handling to homogeneously mix and bioprint human primary mature adipocytes (MA) and adipose-derived stem cells (ASCs), respectively. Accelerated cooling of the bioink turned out to be essential for the homogeneous distribution of lipid-filled MAs in the hydrogel. Last, we compared manual and bioprinted GelMA hydrogels with MA or ASCs and the explanted lobules to evaluate the impact of the printing process and rate the models concerning the physiological reference. The viability analyses demonstrated no significant difference between the groups due to additive manufacturing. The staining of intracellular lipids and perilipin A suggest that GelMA is well suited for ASCs and MA. Therefore, we successfully constructed physiological in vitro models by bioprinting MA-containing GelMA bioinks.
Influence of the respirator on volatile organic compounds : an animal study in rats over 24 hours
(2015)
Long-term animal studies are needed to accomplish measurements of volatile organic compounds (VOCs) for medical diagnostics. In order to analyze the time course of VOCs, it is necessary to ventilate these animals. Therefore, a total of 10 male Sprague–Dawley rats were anaesthetized and ventilated with synthetic air via tracheotomy for 24 h. An ion mobility spectrometry coupled to multi-capillary columns (MCC–IMS) was used to analyze the expired air. To identify background contaminations produced by the respirator itself, six comparative measurements were conducted with ventilators only. Overall, a number of 37 peaks could be detected within the positive mode. According to the ratio peak intensity rat/ peak intensity ventilator blank, 22 peaks with a ratio >1.5 were defined as expired VOCs, 12 peaks with a ratio between 0.5 and 1.5 as unaffected VOCs, and three peaks with a ratio <0.5 as resorbed VOCs. The peak intensity of 12 expired VOCs changed significantly during the 24 h measurement. These results represent the basis for future intervention studies. Notably, online VOC analysis with MCC–IMS is possible over 24 h in ventilated rats and allows different experimental approaches.
Wirtschaft, Gesellschaft und Finanzwelt entwickeln sich dynamisch und unterliegen heute - dies ist schon fast eine Binsenweisheit - einem beschleunigten Wandel. Dennoch basieren die gängigen Managementmethoden für Führungskräfte noch immer auf der Annahme optimaler, stabil-berechenbarer Rahmenbedingungen. Die Autoren gehen jedoch davon aus, dass angesichts sprunghafter Veränderungen der Unternehmensumwelt schnelle und flexible Reaktionen mit einfachen Methoden wichtiger sind als die zeit- und kostenaufwendige Suche nach optimalen Lösungen. Um dennoch gute Ergebnisse zu erreichen, müssen in der betrieblichen Praxis Methoden zum Einsatz kommen, die das Erfahrungswissen und die Intuition einer Gruppe von Kollegen stärker als bisher nutzen - es bedarf eines robusten Managements.
Sol-Gel basierte Flammschutzmittel stellen einen vielversprechenden Ansatz für Textilien dar, gerade im Bereich des Ersatzes von derzeit etablierten halogenhaltigen Flammschutzmitteln. Letztere sind aufgrund ihrer toxikologisch Bedenklichkeit sowie ihrer mitunter bioakkumulierenden Eigenschaften in die Kritik geraten. In diesem Forschungsvorhaben wurde daher untersucht wie aus Phosphor- und stickstoffhaltige Silane halogenfreie Flammschutzmittel verwirklicht werden können. Die Sol-Gel-Schicht fungierte dabei zum einen als nicht brennbarer Binder, zum anderen konnten über das Anbinden von Phosphorgruppen in an kommerziell verfügbare Silane Flammschutz aktive Gruppen direkt mit eingebunden werden. Verschiedene Syntheseansätze wurden dabei verfolgt, wobei durch alle hergestellten N-P-Silane ein Flammschutz nach DIN EN ISO 15025 (Schutzkleidung – Schutz gegen Hitze und Flammen) erhalten wurden. Dabei hängt die Flammschutzwirkung stark von den funktionellen Gruppen und der Oxidationsstufe des Phosphors ab, dabei konnte ein entsprechender Flammschutz bei Auflagen von 5 % erzielt werden. Es konnte gezeigt werden, dass ein Mechanismus auf Basis der Bildung einer Schutzschicht hauptsächlich verantwortlich für den Flammschutz ist. Dieses Ergebnis ist für eine zukünftige, weitere Optimierung entsprechender Ausrüstungen nicht zu unterschätzen. Durch Ausrüstungsversuche im semi-industriellen Maßstab konnte weiterhin gezeigt werden, dass einer großtechnischen Umsetzung der angewandten Ausrüstungen prinzipiell nichts im Wege steht. Je nach funktioneller Gruppe am Phosphor konnte die Wasserlöslichkeit und die Waschstabilität kontrolliert werden. Dabei konnte zum einen gezeigt werden, dass hydrophobes N-P-Silane eine bessere Waschbeständigkeit aufweisen, hydrophile N-P-Silane erhalten diese erst bei Fixierungstemperaturen von 180 °C. Ausgehend von den Ergebnissen konnten sticktstoffgenerierende und cyanursäure-basierte N-P-Silane entwickelt werden, welche sich besonders in einer guten Flammschutzwirkung bei Mischgeweben auszeichnen. Insgesamt konnte innerhalb des Forschungsvorhabens gezeigt werden, dass N-P-Silane hervorragende permanente Flammschutzmittel für Textilien sind und auf welchem Mechanismus dieser Flammschutz begründet ist.
In the IGF project No. 19617 N, nitrogen and phosphorous substituted alkoxysilanes were prepared and their ability to inhibit fire growth and spread for fabrics was explored. To this end, a series of flame retardants were synthesized using different strategies including click chemistry and nucleophilic substitution of commercial organophosphorus compounds with amino-based trialkoxysilanes and/or cyanuric chloride. The new halogen-free and aldehyde-free flame retardants were applied to different fabrics such as cotton (CO), polyethylene terephthalate (PET), polyamide (PA) and their blends using the well-known pad-dry-cure technique and sol-gel method. The flame-retarding efficiencies were evaluated by EN ISO 15025 test methods (protective clothing-protection against heat and flame method of test for limited flame spread). Good flame retardancy of the hybrid organic-inorganic materials was achieved with the addition of as small amount as 3-5 wt.% for cotton fabrics. Moreover, the water solubility and the washing resistance could be controlled through the functional groups attached to the phosphor atom or through the optimization of the curing temperature. Overall, the research project demonstrated that N-P-silanes are very good permanent flame retardants for textiles.
Im IGF-Projekt Nr. 19617 N wurden stickstoff- und phosphorsubstituierte Alkoxysilane hergestellt und ihre flammhemmenden Eigenschaften für Textilien untersucht. Die Synthesen erfolgten nach unterschiedlichen Strategien wie der Klick-Chemie und der nukleophilen Substitution kommerziell erhältlicher Organophosphorverbindungen mit aminobasierten Trialkoxysilanen und/oder Cyanurchlorid. Diese neuartigen, halogen- und aldehydfreien Flammschutzmittel wurden auf Stoffe aus Baumwolle (BW), Polyethylenterephthalat (PET), Polyamid (PA), sowie Mischgeweben daraus mit der industriell etablierten Pad-Dry-Cure-Technik und mittels Sol-Gel-Verfahren aufgetragen. Die flammhemmenden Eigenschaften wurden mit den Prüfverfahren nach EN ISO 15025 (Schutzkleidung – Schutz gegen Hitze und Flammprüfverfahren für begrenzte Flammenausbreitung= bewertet. Eine gute Schwerentflammbarkeit der hybriden organisch-anorganischen Materialien wurde bei einer geringen Menge von 3-5 Gew.% auf Baumwollgeweben erreicht. Darüber hinaus konnten die Wasserlöslichkeit und die Waschbeständigkeit durch die an das Phosphoratom gebundenen funktionellen Gruppen und durch die Optimierung der Härtungstemperatur kontrolliert werden. Insgesamt zeigte das Forschungsprojekt, dass N-P-Silane sehr gute permanente Flammschutzmittel für Textilien sind.
Flame-retardant finishing of cotton fabrics using DOPO functionalized alkoxy- and amido alkoxysilane
(2023)
In the present study, DOPO-based alkoxysilane (DOPO-ETES) and amido alkoxysilane (DOPO-AmdPTES) were synthesized by one-step and without by-products as halogen-free flame retardants. The flame retardants were applied on cotton fabric utilizing sol–gel method and pad-dry-cure finishing process. The flame retardancy, the thermal stability and the combustion ehaviour of treated cotton were evaluated by surface and bottom edge ignition flame test (according to EN ISO 15025), thermogravimetric analysis (TGA) and micro-scale combustion calorimeter (MCC). Unlike CO/DOPO-ETES sample, cotton treated with DOPO-AmdPTES nanosols exhibits self-extinguishing ehaviour with high char residue, an improvement of the LOI value and a significant reduction of the PHRR, HRC and THR compared to pristine cotton. Cotton finished with DOPO-AmdPTES reveals a semi-durability after ten laundering cycles keeping the flame-retardant properties unchanged. According to the results obtained from TGA-FTIR, Py-GC/MS and XPS, the major activity of flame retardant occurs in the condensed phase via catalytic induced char formation as physical barrier along with the activity in the gas phase derived mainly from the dilution effect. The early degradation of CO/DOPO-AmdPTES compared to CO/DOPO-ETES, triggered by the cleavage of the weak bond between P and C=O, as the DFT study indicated, provides the beneficial effect of this flame retardant on the fire resistance of cellulose.
The chemical recycling of used motor oil via catalytic cracking to convert it into secondary diesel-like fuels is a sustainable and technically attractive solution for managing environmental concerns associated with traditional disposal. In this context, this study was conducted to screen basic and acidic-aluminum silicate catalysts doped with different metals, including Mg, Zn, Cu, and Ni. The catalysts were thoroughly characterized using various techniques such as N2 adsorption–desorption isotherms, FT-IR spectroscopy, and TG analysis. The liquid and gaseous products were identified using GC, and their characteristics were compared with acceptable ranges from ASTM characterization methods for diesel fuel. The results showed that metal doping improved the performance of the catalysts, resulting in higher conversion rates of up to 65%, compared to thermal (15%) and aluminum silicates (≈20%). Among all catalysts, basic aluminum silicates doped with Ni showed the best catalytic performance, with conversions and yields three times higher than aluminum silicate catalysts. These findings significantly contribute to developing efficient and eco-friendly processes for the chemical recycling of used motor oil. This study highlights the potential of basic aluminum silicates doped with Ni as a promising catalyst for catalytic cracking and encourages further research in this area.
Fast pyrolysis as a valorization mechanism for banana rachis and low-density polyethylene waste
(2021)
Banana rachis and low-density polyethylene (LDPE) were selected as secondary feedstocks for the study of fast pyrolysis in a free-fall reactor. The experiments were performed at 600 °C for banana rachis and 450 °C for LDPE, based on literature and thermogravimetric analysis. The gaseous products of both feedstocks present similar composition in the C1-C2 compounds, while C3 compounds are only found in LDPE. The liquid products from banana and LDPE correspond to functional groups and shorter hydrocarbons, respectively. Scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) analyses of the char showed important morphological changes to spheres in LDPE and structural changes due to thermal decomposition in the biomass. The pyrolysis char has high potential as adsorbent, encapsulation, or catalyst.
Characterization of low density polyethylene greenhouse films during the composting of rose residues
(2022)
This study presents an evaluation of a potential alternative to plastic degradation in the form of organic composting. It stems from the urgent need of finding solutions to the plastic residues and focuses on the compost-based degradation of greenhouse film covers in an important rose exporter company in Ecuador. Thus, this study analyzes the physical, chemical, and biological changes of rose wastes composting, and also evaluates the stability of new and aged agricultural plastic under these conditions. Interestingly, results of compost characterization show a slow degradation rate of organic matter and total organic carbon, along with a significant increase in pH and rise of bacterial populations. However, the results demonstrate that despite these findings, composting conditions had no significant influence on plastic degradation, and while deterioration of aged plastic samples was reported in some tests, it may be the result of environmental conditions and a prolonged exposure to solar radiation. Importantly, these factors could facilitate the adhesion of microorganisms and promote plastic biodegradation. Hence, it is encouraged for future studies to analyze the ecotoxicity of plastics in the compost, as well as isolate, identify, and evaluate the possible biodegradative potential of these microorganisms as an alternative to plastic waste management.
While there has been increased digitization of private homes, only little has been done to understand these specific home technologies, how they serve consumers, among other issues. “Smart home technology” (SHT) refer to a wide range of artifacts from cleaning aids to energy advisors. Given this breadth, clarity surrounding the key characteristics and the multi-faceted impact of SHT is needed to conduct more directed research on SHT. We propose a taxonomy to help outline the salient intended outcomes of SHT. Through a process involving five iterations, we analyzed and classified 79 technologies (gathered from literature and industry reports). This uncovered seven dimensions encompassing 20 salient characteristics. We believe these dimensions/characteristics will help researchers and organizations better design and study the impacts of these technologies. Our long-term agenda is to use the proposed taxonomy for an exploratory inquiry to understand tensions occurring when personal and sustainability-related outcomes compete.
In times of climate change and growing urbanization, the way food is produced and consumed also changes. Meanwhile, digitization is transforming farming practices, which also applies to the domestic growing of crops. More and more so-called smart home farms (SHF) are finding their way into private households. This paper conceptualizes the unique nature of enabled smart services and their underlying technology. Following an inductive interpretive approach, this study explores the antecedents of smart home farming practices. Our sample consists of eleven actual smart home farmers. We found six constructs to be of salient importance: expected outcomes related to harvesting, positive feelings, and sustainability; a combination of one's affinity for green and novel technologies; and the smartness and visibility of the enabled services. In the outlook, we present some preliminary thoughts for testing our qualitative findings.
Facing ever-looming climate change, studying the drivers for individuals' Information Systems (IS) Use to reduce environmental harm gains momentum. While extant research on the antecedents of sustainable IS Use has focused on specific theories, interventions, contexts, and technologies, a holistic understanding has become increasingly elusive, with a synthesis remaining absent. We employ a systematic literature review methodology to shed light on the driving antecedents for sustainable IS Use among individual consumers. Our results build on findings of 29 empirical studies drawn from 598 articles retrieved from our premier outlets and a forward/backward search. The analysis reveals six salient complementary antecedents: Relief, Empowerment, Default, User-centricity, Salience, and Encouragement. We recommend considering these concepts when developing, deploying, promoting, or regulating digital technologies to mitigate individual consumers' emissions. Along with memorable and implementable concepts, our theoretical framework offers a novel conceptualization and four promising avenues for researchers on sustainable IS Use.
The proliferation of smart technologies transforms the way individual consumers perform tasks. Considerable research alludes that smart technologies are often related to domestic energy consumption. However, it remains unclear how such technologies transform tasks and thereby impact our planet. We explore the role of technological smartness in personal day-to-day tasks that help create a more sustainable future. In the absence of theory, but facing extensive changes in everyday life enabled by smart technologies, we draw on phenomenon-based theorizing (PBT) guidelines. As anchor, we refer to task endogeneity related to task-technology fit theory (TTF). As infusion, we employ theory on public goods. Our model proposes novel relations between the concepts of smart autonomy and -transparency with sustainable task outcomes, mediated by task convenience and task significance. We discuss some implications, limitations, and future research opportunities.
The effect of Hofmeister anions on the surface properties of polyelectrolyte multilayers built from hyaluronan and chitosan by layer-by-layer deposition is studied by ellipsometry and atomic force microscopy. The thickness, roughness and morphology of the resulting coatings were found to depend on the type of the anion. Relationship between the surface properties and the biological response of the polyelectrolyte multilayers is established by assessing the degree of protein (albumin) adsorption.
The properties of polyelectrolyte multilayers are ruled by the process parameters employed during self-assembly. This is the first study in which a design of experiment approach was used to validate and control the production of ultrathin polyelectrolyte multilayer coatings by identifying the ranges of critical process parameters (polyelectrolyte concentration, ionic strength and pH) within which coatings with reproducible properties (thickness, refractive index and hydrophilicity) are created. Mathematical models describing the combined impact of key process parameters on coatings properties were developed demonstrating that only ionic strength and pH affect the coatings thickness, but not polyelectrolyte concentration. While the electrolyte concentration had a linear effect, the pH contribution was described by a quadratic polynomial. A significant contribution of this study is the development of a new approach to estimate the thickness of polyelectrolyte multilayer nanofilms by quantitative rhodamine B staining, which might be useful in all cases when ellipsometry is not feasible due to the shape complexity or small size of the coated substrate. The novel approach proposed here overcomes the limitations of known methods as it offers a low spatial sampling size and the ability to analyse a wide area without restrictions on the chemical composition and shape of the substrate.
Controlling the surface properties and structure of thin nanosized coatings is of primary importance in diverse engineering and medical applications. Here we report on how the nanostructure, growth mechanism, thickness, roughness, and hydrophilicity of nanocomposites composed of weak natural or strong synthetic polyelectrolytes (PE) can be tailored by graphene oxide (GO) doping. GO reverses the build‐up mechanism affecting the internal structure and the hydrophilicity in a way depending on the type of the PE‐matrix. The extent of GO‐adsorption and its impact on the surface morphology was found to be independent on the type of the underlying PE‐matrix. The nanostructure of the hybrid films is not significantly altered when a single surface‐exposed GO‐layer is deposited, while increasing the number of embedded GO‐layers leads to pronounced surface heterogeneity. These results are expected to have valuable impact on the construction strategies of coatings with tunable surface properties.
Herein the optimization of the physicochemical properties and surface biocompatibility of polyelectrolyte multilayers of the natural, biocompatible and biodegradable, linear polysaccharides hyaluronan and chitosan by Hofmeister anions was systematically investigated. We demonstrated that there is an interconnection between the bulk and surface properties of HA/Chi multilayers both varying in accordance with the arrangement of the anions in the Hofmeister series. Kosmotropic anions increased the hydration, thickness, micro- and macro-roughness, and hydrophilicity and improved the biocompatibility of the films by reduction (2 orders of magnitude) of the films stiffness and complete anti-thrombogenicity.
The proper selection of a demand forecasting method is directly linked to the success of supply chain management (SCM). However, today’s manufacturing companies are confronted with uncertain and dynamic markets. Consequently, classical statistical methods are not always appropriate for accurate and reliable forecasting. Algorithms of Artificial intelligence (AI) are currently used to improve statistical methods. Existing literature only gives a very general overview of the AI methods used in combination with demand forecasting. This paper provides an analysis of the AI methods published in the last five years (2017-2021). Furthermore, a classification is presented by clustering the AI methods in order to define the trend of the methods applied. Finally, a classification of the different AI methods according to the dimensionality of data, volume of data, and time horizon of the forecast is presented. The goal is to support the selection of the appropriate AI method to optimize demand forecasting.
The early involvement of experiences gained through intelligence and data analysis is becoming increasingly important in order to develop new products, leading to a completely different conception of product creation, development and engineering processes using the advantages that the dedication of the digital twin entails. Introducing a novel stage gate process in order to be holistically anchored in learning factories adopting idea generation and idea screening in an early stage, beta testing of first prototypes, technical implementation in real production scenarios, business analysis, market evaluation, pricing, service models as well as innovative social media portals. Corresponding product modelling in the sense of sustainability, circular economy, and data analytics forecasts the product on the market both before and after market launch with the interlinking of data interpretation nearby in real-time. The digital twin represents the link between the digital model and the digital shadow. Additionally, the connection of the digital twin with the product provides constantly updated operating status and process data as well as mapping of technical properties and real-world behaviours. A future-networking product, by embedded information technology with the ability to initiate and carry out one's own further development, is able to interact with people and environments and thus is relevant to the way of life of future generations. In today's development work for this new product creation approach, on one hand, "Werk150" is the object of the development itself and on the other hand the validation environment. In the next step, new learning modules and scenarios for trainings at master level will be derived from these findings.
Das Ziel dieser Arbeit war die Umsetzung eines Wahrnehmungsensors für Softwareagenten, die über ein virtuelles Menschmodell in einer dreidimensionalen Umgebung agieren. Hierbei sollen die Agenten über den Sensor in der Lage sein, semantische Informationen zu geometrischen Objekten in der Umgebung zu erhalten. Hierfür wurden zwei Verfahren umgesetzt, die das menschliche Sehen simulieren, indem Objekte erkannt werden, wenn diese innerhalb eines Sichtfelds liegen. Ein Problem, das dabei gelöst werden muss, ist die Identifizierung möglicher Verdeckungen der Objekte. Ein Ansatz, dieses Problem zu lösen, ist der Ray-Tracing Ansatz, welcher für das erste Verfahren umgesetzt wurde. Das zweite Verfahren verwendet den Occlusion-Culling Ansatz. Auswertungen beider Verfahren haben gezeigt, dass der Ray-Tracing Ansatz eine schnellere Laufzeit aufweist, der Occlusion-Culling Ansatz jedoch mehr unverdeckte Objekte im Sichtfeld erkennt.
In dieser Arbeit werden Anforderungen an ein digitales Referenzmodell der Cell and Gene Therapy (CGT) Supply Chain mittels systematischer Literaturrecherche unter partieller Anwendung der Preferred-Reporting-Items-for-Systematic-Reviews-and-Meta-Analyses(PRISMA)-2020-Methode erarbeitet und erläutert. Die Ergebnisse der Literaturrecherche untermauern, dass die CGT Supply Chain standardisierte und automatisierte Prozesse benötigt, gewissen Transportanforderungen gerecht werden sowie eine lückenlose Rückverfolgbarkeit gewährleisten können muss. Die Anforderungen an das Referenzmodell lehnen sich z. T. an die Anforderungen des klassischen Supply-Chain-Operations-Reference(SCOR)-Modells an, bedürfen jedoch einer Veränderung und Weiterentwicklung unter Beachtung der Besonderheiten der CGT Supply Chain. Auf Basis eines Referenzmodells für die CGT Supply Chain, das die aus dieser Arbeit identifizierten Anforderungen beachtet, kann eine übergeordnete Managementplattform aufgebaut werden. Mit der digitalen Abbildung und Vernetzung aller Aktivitäten ist der Grundstein für die Integration in ein Enterprise-Resource-Planning(ERP)-System zum effektiven Data und Process Mining gelegt. Durch eine zunehmend bessere Datenqualität und -quantität entlang der Prozesse der CGT Supply Chain lassen sich verstärkt Informationen über die Prozesse selbst generieren, aus denen weitere Verbesserungsansätze hervorgehen. Eine CGT-Managementplattform bildet demnach die Grundlage für alle Prozesse innerhalb der CGT Supply Chain für einen kontinuierlichen Verbesserungsprozess.
Seit 10 Jahren lehrt der Künstler Henning Eichinger an der Hochschule Reutlingen. Was als künstlerische Unterstützung für Textil- und Modedesign-Studenten begann, hat sich mittlerweile zu einer ganz eigenständigen Position entwickelt. Aus dem Designstudium sind einige national und international erfolgreiche junge Künstler und Designer hervorgegangen. Sieben von ihnen werden zusammen mit Henning Eichinger in der Ausstellung präsentiert.
This paper is concerned with the study, optimization and control of the moisture sorption kinetics of agricultural products at temperatures typically found in processing and storage. A nonlinear autoregressive with exogenous inputs (NARX) neural network was developed to predict moisture sorption kinetics and consequently equilibrium moisture contents of shiitake mushrooms (Lentinula edodes (Berk.) Pegler) over a wide range of relative humidity and different temperatures. Sorption kinetic data of mushroom caps was separately generated using a continuous, gravimetric dynamic vapour sorption analyser at emperatures of 25-40 °C over a stepwise variation of relative humidity ranging from 0 to 85%. The predictive power of the neural network was based on physical data, namely relative humidity and temperature. The model was fed with a total of 4500 data points by dividing them into three subsets, namely, 70% of the data was used for training, 15% of the data for testing and 15% of the data for validation, randomly selected from the whole dataset. The NARX neural network was capable of precisely simulating equilibrium moisture contents of mushrooms derived from the dynamic vapour sorption kinetic data throughout the entire range of relative humidity.
We study whether compulsory religious education in schools affects students' religiosity as adults. We exploit the staggered termination of compulsory religious education across German states in models with state and cohort fixed effects. Using three different datasets, we find that abolishing compulsory religious education significantly reduced religiosity of affected students in adulthood. It also reduced the religious actions of personal prayer, church-going, and church membership. Beyond religious attitudes, the reform led to more equalized gender roles, fewer marriages and children, and higher labor-market participation and earnings. The reform did not affect ethical and political values or non-religious school outcomes.
We study whether compulsory religious education in schools affects students' religiosity as adults. We exploit the staggered termination of compulsory religious education across German states in models with state and cohort fixed effects. Using three different datasets, we find that abolishing compulsory religious education significantly reduced religiosity of affected students in adulthood. It also reduced the religious actions of personal prayer, church-going, and church membership. Beyond religious attitudes, the reform led to more equalized gender roles, fewer marriages and children, and higher labor-market participation and earnings. The reform did not affect ethical and political values or non-religious school outcomes.
Being exposed to compulsory religious education in school can have long-run consequences for students’ lives. At different points in time since the 1970s, German states terminated compulsory religious education in public schools and replaced it by a choice between ethics classes and religious education. This article shows that the reform not only led to reduced religiosity in students’ later life, but also eroded traditional attitudes towards gender roles and increased labor-market participation and earnings.
Nowadays, the importance of early active patient mobilization in the recovery and rehabilitation phase has increased significantly. One way to involve patients in the treatment is a gamification-like approach, which is one of the methods of motivation in various life processes. This article shows a system prototype for patients who require physical activity because of active early mobilization after medical interventions or during illness. Bedridden patients and people with a sedentary lifestyle (predominantly lying in bed) are also potential users. The main idea for the concept was non-contact system implementation for the patients making them feel effortless during its usage. The system consists of three related parts: hardware, software, and game application. To test the relevance and coherence of the system, it was used by 35 people. The participants were asked to play a video game requiring them to make body movements while lying down. Then they were asked to take part in a small survey to evaluate the system's usability. As a result, we offer a prototype consisting of hardware and software parts that can increase and diversify physical activity during active early mobilization of patients and prevent the occurrence of possible health problems due to predominantly low activity. The proposed design can be possibly implemented in hospitals, rehabilitation centers, and even at home.
Monitoring heart rate and breathing is essential in understanding the physiological processes for sleep analysis. Polysomnography (PSG) system have traditionally been used for sleep monitoring, but alternative methods can help to make sleep monitoring more portable in someone's home. This study conducted a series of experiments to investigate the use of pressure sensors placed under the bed as an alternative to PSG for monitoring heart rate and breathing during sleep. The following sets of experiments involved the addition of small rubber domes - transparent and black - that were glued to the pressure sensor. The resulting data were compared with the PSG system to determine the accuracy of the pressure sensor readings. The study found that the pressure sensor provided reliable data for extracting heart rate and respiration rate, with mean absolute errors (MAE) of 2.32 and 3.24 for respiration and heart rate, respectively. However, the addition of small rubber hemispheres did not significantly improve the accuracy of the readings, with MAEs of 2.3 bpm and 7.56 breaths per minute for respiration rate and heart rate, respectively. The findings of this study suggest that pressure sensors placed under the bed may serve as a viable alternative to traditional PSG systems for monitoring heart rate and breathing during sleep. These sensors provide a more comfortable and non-invasive method of sleep monitoring. However, the addition of small rubber domes did not significantly enhance the accuracy of the readings, indicating that it may not be a worthwhile addition to the pressure sensor system.
Sleep analysis using a Polysomnography system is difficult and expensive. That is why we suggest a non-invasive and unobtrusive measurement. Very few people want the cables or devices attached to their bodies during sleep. The proposed approach is to implement a monitoring system, so the subject is not bothered. As a result, the idea is a non-invasive monitoring system based on detecting pressure distribution. This system should be able to measure the pressure differences that occur during a single heartbeat and during breathing through the mattress. The system consists of two blocks signal acquisition and signal processing. This whole technology should be economical to be affordable enough for every user. As a result, preprocessed data is obtained for further detailed analysis using different filters for heartbeat and respiration detection. In the initial stage of filtration, Butterworth filters are used.
We report the temperature dependence of metal-enhanced fluorescence (MEF) of individual photosystem I (PSI) complexes from Thermosynechococcus elongatus (T. elongatus) coupled to gold nanoparticles (AuNPs). A strong temperature dependence of shape and intensity of the emission spectra is observed when PSI is coupled to AuNPs. For each temperature, the enhancement factor (EF) is calculated by comparing the intensity of individual AuNP-coupled PSI to the mean intensity of ‘uncoupled’ PSI. At cryogenic temperature (1.6 K) the average EF was 4.3-fold. Upon increasing the temperature to 250 K the EF increases to 84-fold. Single complexes show even higher EFs up to 441.0-fold. At increasing temperatures the different spectral pools of PSI from T. elongatus become distinguishable. These pools are affected differently by the plasmonic interactions and show different enhancements. The remarkable increase of the EFs is explained by a rate model including the temperature dependence of the fluorescence yield of PSI and the spectral overlap between absorption and emission spectra of AuNPs and PSI, respectively.
Cyber-Physical Production Systems increasingly use semantic information to meet the grown flexibility requirements. Ontologies are often used to represent and use this semantic information. Existing systems focus on mapping knowledge and less on the exchange with other relevant IT systems (e.g., ERP systems) in which crucial semantic information, often implicit, is contained. This article presents an approach that enables the exchange of semantic information via adapters. The approach is demonstrated by a use case utilizing an MES system and an ERP system.
Thermoplastic polycarbonate urethane elastomers (TPCU) are potential implant materials for treating degenerative joint diseases thanks to their adjustable rubber-like properties, their toughness, and their durability. We developed a water-containing high-molecular-weight sulfated hyaluronic acid-coating to improve the interaction of TPCU with the synovial fluid. It is suggested that trapped synovial fluid can act as a lubricant that reduces the friction forces and thus provides an enhanced abrasion resistance of TPCU implants. Aims of this work were (i) the development of a coating method for novel soft TPCU with high-molecular sulfated hyaluronic acid to increase the biocompatibility and (ii) the in vitro validation of the functionalized TPCUs in cell culture experiments.
Knee osteoarthritis is a common complication and can lead to total loss of joint function in patients. Treatment by either partial or total knee replacement with appropriate UHMWPE based implantsis highly invasive, may cause complications and may show unsatisfying results. Alternatively, treatment may be done by insertion of an elastic interpositional knee spacer with optimized material characteristics.
We report the development of high performance polyurethane-based polymers modified with bioactive molecules for fabrication of such knee spacers. In order to tailor mechanical and tribological properties and to improve resist to enzymatic degradation we propose a core-shell model for the spacer with specifically adapted properties.
Polyurethane-bases block copolymers (TPCUs) are block-copolymers with systematically varied soft and hard segments. They have been suggested to serve as material for chondral implants in joint regeneration. Such applications may require the adhesion of chondrocytes to the implant surface, facilitating cell growth while keeping their phenotype. Thus, aims of this work were (1) to modify the surface of soft biostable polyurethane-based model implants (TPCU and TSiPCU) with high-molecular weight hyaluronic acid (HA) using an optimized multistep strategy of immobilization, and (2) to evaluate bioactivity of the modified TPCUs in vitro. Our results show no cytotoxic potential of the TPCUs. HAbioactive molecules (Mw =700kDa) were immobilized onto the polyurethane surface via polyethylenimine (PEI) spacers, and modifications were confirmed by several characterization methods. Tests with porcine chondrocytes indicated the potential of the TPCU-HA for inducing enhanced cell proliferation.
Die Kompetenzentwicklung in virtuellen, internationalen Teams ist eine zentrale Herausforderung für alle international agierenden Unternehmen, denn Studien zufolge hängt der Unternehmenserfolg auf den internationalen Märkten stark von der Kompetenz der Mitarbeiter ab. Der Aufbau der Kompetenzen zum Management virtueller, internationaler Teams muss im Zusammenhang immer komplexer werdender Geschäftsmodelle betrachtet werden. Diese Geschäftsmodelle erfordern eine umfangreiche Interaktion von Mitarbeitern in globalen Teams. Die Mitarbeiter stehen darin vor der Herausforderung, verschiedene Aspekte der Zusammenarbeit in unterschiedlichen Dimensionen zu beherrschen, die sich aus dem Arbeitsumfeld ergeben.
Da der Erfolg virtueller, internationaler Teams sowohl von den Kompetenzen jedes einzelnen Teammitglieds als auch der teaminternen Kooperationskompetenz abhängt, ist es wichtig, die erforderlichen Kompetenzen zu analysieren, die vorhandene Kompetenzen zu bewerten und entsprechend der Anforderungen weiterzuentwickeln.
In den Buchbeiträgen werden Vorgehensmodelle für die Kompetenzentwicklung in virtuellen, internationalen Teams für die Kompetenzfelder Interkulturelles Management, Methodikkompetenz und Führungskompetenz vorgestellt und die Inhalte der Kompetenzfelder im Detail diskutiert.
Fähigkeits- und Reifegradmodelle (Capability Maturity Models CMM) bilden die wesentlichen Elemente effizienter Prozesse ab und helfen, diese so zu organisieren und auszuführen, dass eine hohe Wertigkeit des Prozesses bzw. des Produktes bzgl. Zeit-, Kosten- und Qualitätsgesichtspunkten entsteht. Es gibt zwar inzwischen sehr viele Reifegradmodelle am Markt, die von Institutionen und Beratungsfirmen entwickelt wurden, allerdings keines, das sich mit dem Management virtueller, internationaler Teams im Speziellen befasst.
Basierend auf der Reifegradmodellstruktur nach CMMI werden in den Buchbeiträgen Reifegradmodelle für die Bewertung virtueller, internationaler Teams vorgestellt. Neben der Reifegradstruktur werden insbesondere die Inhalte zur Bewertung der Reifegradstufen für verschiedene Schwerpunkte im Detail über mehre Gliederungsebenen heruntergebrochen, so dass ein sehr umfassendes Reifegradbewertungsschema vorliegt. Die Schwerpunktthemen sind Fachkompetenz, interkulturelle Kompetenz, Teambesprechungen, Führungseffektivität und -effizienz sowie der Einsatz von Informations- und Kommunikationstechnologien (IKT).
Zur Führung eines virtuellen, internationalen Teams bedarf es Führungsinstrumente, zu denen u.a. auch Kennzahlensysteme gehören. Allerdings gestaltet sich die Festlegung von geeigneten Kennzahlen für derartige Teams schwierig, da die Komplexität der Zusammenarbeit, mit der sie konfrontiert sind, aufgrund der räumlichen Trennung und der interkulturellen Unterschiede sehr hoch ist und teilweise starke Wechselwirkungen zwischen einzelnen Bewertungsaspekte auftreten können. Außerdem müssen sehr unterschiedliche Aspekte aus Unternehmens- und Teamsicht bei der Erfolgsbewertung betrachtet werden.
In den Buchbeiträgen werden Methodiken und Kennzahlensysteme zur Leistungsmessung und -bewertung in virtuellen, internationalen Teams entwickelt und die Kennzahlen darin im Detail betrachtet und dargestellt. Die Schwerpunktthemen umfassen die Bereiche Führung, Projektmanagement, Teambesprechungen, Fachwissen und Einsatz von Informations- und Kommunikationstechnologien.
Für virtuelle, internationale Teams sind Kommunikationstechnologien ein wichtiges Werkzeug, da aufgrund der räumlichen Trennung eine face-to-face-Kommunikation i.d.R. nur selten möglich ist. Sie muss durch Kommunikation ersetzt werden, die mittels Kommunikationstechnologien erfolgt. In den letzten Jahren haben vor allem die Web 2.0 Technologien neue Möglichkeiten der Kommunikation geschaffen. Herkömmliche Kommunikationsformen, wie Telefon, Email und Videokonferenzen werden durch Web 2.0 Technologien ergänzt.
Für die Bewertung des Nutzens, der Chancen und Risiken von Kommunikationstechnologien ist die SWOT-Analyse (Strength-Weakness-Opportunities-Threads-Analyse) eine gut einsetzbare Methode zur Strukturierung und Detaillierung von Bewertungskriterien.
In den Buchbeiträgen werden insbesondere basierend auf der SWOT-Analyse verschiedene Anwendungen von Web 2.0 Technologien für virtuelle, internationale Teams mit den Schwerpunkten Foren und Blogs, Virtuelle Meeting Rooms, Virtuelle Welten und Soziale Netzwerke analysiert und bewertet. Außerdem werden rechtliche Aspekte bei der Nutzung Offener Sozialer Netzwerke für verschiedene, am Markt agierende Anbieter diskutiert und die Auswirkungen auf virtuelle, internationale Teams anhand realer Beispiele genauer untersucht. Abschließend wird ein Konzept einer idealtypischen ITK-Plattform vorgestellt, mit der virtuelle, internationale Teams ihre Arbeitsweise verbessern können.
In Logistiknetzwerken stellen Lager einen wichtigen, aber zugleich kostenintensiven Faktor dar. Mit modernen Lagermanagement-Methoden zur Prozessoptimierung und Technologieausnutzung können Sie in Ihrer Lagerlogistik erhebliche Kosten einsparen und die Qualität erhöhen. Der neue Ansatz dazu heißt Lean Warehousing. Lean Warehousing bedeutet Prozessverbesserung mit einfachen Mitteln. Low Cost Automatisation und Ablaufverbesserungen im Einklang mit der Technik sind – nicht nur in wirtschaftlich schwierigen Zeiten – eine gewinnbringende Investition in die Zukunft.
Die neue DIN EN ISO 9001:2015 ist ein Meilenstein in der Normenentwicklung, da mit ihr die Zusammenführung unterschiedlicher Strukturen verschiedener Managementnormen erfolgt, die jetzt alle nach dem gleichen System strukturiert sind bzw. in Zukunft noch derart strukturiert werden. Außerdem spezifiziert sie Anforderungen in einigen Bereichen deutlich genauer und umfangreicher als dies bisher der Fall war. Dementsprechend müssen Unternehmen für eine Neu- oder Reakkreditierung ihre Organisation weiterentwickeln. Der folgende Artikel gibt einen Überblick über wesentliche Änderungen und den anzustrebenden Umgang damit.
Management virtueller, internationaler Engineering-Prozesse. - (Berichte aus dem Maschinenbau)
(2017)
Die Internationalisierung von Geschäftsprozessen hat dazu geführt, dass in den Engineering-Prozessen, z.B. Produktentwicklung, Produktionsplanung etc., zunehmend in virtuellen, internationalen Teams gearbeitet wird. Die Prozesse und Methoden wurden aber oft nicht entsprechend weiterentwickelt, dass die virtuellen, internationalen Engineering-Prozesse effektiv und effizient ausgeführt werden. In Rahmen einer fragebogenbasierten Unternehmensbefragung in Deutschland wird untersucht, wie Unternehmen mit Kernfragen der Gestaltung virtueller, internationaler Engineering-Prozesse umgehen und welche Vorgehensweisen, Methoden und Werkzeuge, insbesondere Informations- und Kommunikationstechnologien, sie einsetzen. Dabei werden neben dem Nutzen auch die Risiken thematisiert, die nach der neuen DIN EN ISO 9001:2015 stärker in den unternehmerischen Fokus rücken müssen.
Es gibt viele und teilweise sehr unterschiedliche Vorgehensweisen für die Planung von Materialflusssysstemen in der Produktionslogisitk. Ein spezifisches Vorgehensmodell für die Planung der Produktionsversorgung in der Montage im engeren Sinne existiert nicht. Im Folgenden wird ein solches Vorgehensmodell dargestellt, das sich auf die Planung der Produktionsversorgung fokussiert.
In Logistiknetzwerken stellen Lager einen wichtigen, aber zugleich kostenintensiven Faktor dar. Mit modernen Lagermanagement Methoden zur Prozessoptimierung und Technologieausnutzung können Sie in Ihrer Lagerlogistik erhebliche Kosten einsparen und die Qualität erhöhen. Der neue Ansatz dazu heißt Lean Warehousing. Lean Warehousing bedeutet Prozessverbesserung mit einfachen Mitteln. Low Cost Automatisation und Ablauf-verbesserungen im Einklang mit der Technik sind – nicht nur in wirtschaftlich schwierigen Zeiten – eine gewinnbringende Investition in die Zukunft.
Die Digitalisierung vrändert die Arbeitsweisen in Unternehmen und damit auch bei der Planung von Fabriken. Am Markt verfügbar sind vielfältige Soft- und Hardwaresysteme für die Digitale Fabrik, die die Fabrikplanung unterstützen und teilweise revolutionieren können. Um dieses Potential zu nutzen, muss aber bekannt sein, was diese Systeme können und wie sie sinnvoll genutzt werden können. Bisherige Fabrikplanungssystematiken haben hierzu keine Unterstützung angeboten, da sie nur das generelle Vorgehen der Fabrikplanung beschreiben, ohne den Zusammenhang zu den sich rasch entwickelnden Soft- und Hardwaresystemen herzustellen. Im Folgenden wird die Entwicklung und Umsetzung eines Planungsvorgehens für die Digitale Fabrikplanung dargestellt, das die Potentiale der Soft- und Hardwaresysteme für die Digitale Fabrik aufgreift und in ein passendes Planungsvorgehensmodell integriert.
Innovation-HUBs sind aktuell in Mode. Allerdings beklagen viele Unternehmen, dass der nachhaltige Erfolg aus verschiedenen Gründen nicht ausreichend erzielt wird. Eine Tischtennisplatte und ein Basketballkorb sind eben keine Innovationsgaranten, sondern viel mehr die Mitarbeiter selbst, die ins Zentrum des Innovation-HUBs gestellt werden müssen. Es wird ein Qualifizierungsmodell für die Arbeit in Innovation-HUBs vorgestellt, das auf einem Innovation-HUB-Trainingscenter basiert, das an der Hochschule Reutlingen in der Ausbildung von Studierenden betrieben wird. Hier lernen die Studierenden, wie Sie durch Ihr Verhalten Innovationen treiben oder hemmen und wie sie nachhaltig den Erfolg eines Innovation-HUBs gestalten.
Fabrikplanungsprozesse werden zunehmend durch räumlich und zeitlich verteilte Teams durchgeführt, die agiles Projektmanagement praktizieren. Voraussetzung für den Erfolg ist die Anwendung von Planungssystemen der Digitalen Fabrik sowie moderner Groupware zur Kommunikation, Koordination und Kooperation in den agilen Projektgruppen der jeweiligen Planungsphase. Es wird ein Konzept mit Implementierungshinweisen für einen zukunftsfähigen Fabrikplanungsprozess mit digitalen Systemen vorgestellt.
An die Produktionslogistik werden komplexe
Anforderungen gestellt, so dass eine systematische Vorgehensweise zu deren Planung erforderlich ist. Aufgrund der Abhängigkeiten in der Supply Chain muss die Produtkionslogistik immer vom Lieferanten beginnend geplant werden. Trotz der Vielfalt an Planungssystematiken bieten diese alle nur sehr wenig Unterstützung bei der Gestaltung der einzelnen Planungsobjekte in der Logistikkette an, sodass die Planung und Lösungsfindung häufig intuitiv erfolgt und sehr stark vom individuellen Erfahrungswissen des Logistikplaners abhängt. Im Folgenden wird eine Planungssystematik, die auf Morphologien basiert, vorgestellt, die eine durchgängige Planung von Produktionslogistiksystemen ermöglicht und den Planer umgfangreich mit Informationen zu Gestaltungsmöglichkeiten und praktischen Umsetzungen unterstützt.
Die OLED-Technologie wurde vor über zehn Jahren als Revolution in der Verpackungs-industrie gefeiert, die jedoch in der Praxis ausblieb. In einem industriellen Kooperations-projekt zur Zukunftsszenarienentwicklung der pharmazeutischen Verpackungsindustrie stellt sich die OLED-Technologie als Schlüsseltechnologie für das Zukunftsszenario Smart Packaging 2.0 dar.
Die pharmazeutische Verpackungsindustrie ist durch umfangreiche Regularien geprägt und daher in der Innovationsdynamik etwas eingeschränkt. In einem sechsmonatigen Projekt zur Entwicklung von Zukunftsszenarien für die Pharmaverpackung wurde aufgezeigt, dass zwar neue Technologien, wie E-Labels oder Kindersicherungen, die Marktreife erreicht haben oder in Kürze erreichen werden, neue Anforderungen in absehbarer Zukunft aber weiteren Entwicklungsbedarf erfordern. Die pharmazeutische Verpackungsindustrie muss sich zusammen mit ihren Kunden und Technologielieferanten enger und intensiver austauschen, um die nächste Verpackungsgeneration, Smart Packaging 2.0, auf den Weg zu bringen.
Sichtprüfungen von Produktoberflächen werden überwiegend von Mitarbeitern ausgeführt, wobei Automatisierungsansätze mit Kamera- und Bildverarbeitungssystemen großes Potenzial zeigen. Auch Cobots werden in Qualitätssicherungsprozesse einbezogen.Im Folgenden werden die Integrationsmöglichkeiten von Cobots in die Sichtprüfung diskutiert und ein Entscheidungsmodell dargestellt, mit dem Sichtprüfungsprozesse auf ihre Cobot-Tauglichkeit überprüft werden können. Das Entscheidungsmodell ist für die direkte Integration in bereits existierende Cobot-Eignungsuntersuchungsverfahren konzipiert und dient als erste strategische Entscheidungshilfe.
Mangels durchgängiger Datenstandards für Planungssysteme der Digitalen Fabrik müssen systemspezifische Datenaustauschlösungen implementiert werden. Zur Unterstützung der Planung ist ein durchgängiger Fabrikplanungsprozess mit integrierter Routenplanung sowohl prozess- als auch systemtechnisch erforderlich. Dafür werden beispielhaft ein Fabrik- und ein Routenplanungssystem auf ihre Kompatibilität untersucht, erforderliche Anforderungen abgeleitet und eine Datenaustausch-möglichkeit für den Anwender aufgezeigt.
Für die digitale 3D-VR-Fabrikplanung sind unterschiedliche Soft- und Hardwaresysteme am Markt verfügbar, die teilweise erhebliche Kompatibilitätsprobleme aufweisen. Für die Bewertung der Hardwareeignung für die 3D-VR-Fabrikplanung wird ein Bewertungssystem vorgestellt, das anhand konkreter Softwareapplikationen und einem passiven 3D-Stereo-Monitor mit Head-Tracking erläutert wird. Es wird dazu auch die Notwendigkeit des Einsatzes von Software-Middleware zur Nutzungssteigerung diskutiert.
Durch die demografische Entwicklung und den Fachkräftemangel sichern sich in Zukunft nur die attraktivsten Unternehmen die klügsten Köpfe. Um im "war for talents" erfolgreich zu sein, investieren Unternehmen in zukunftsfähige Recruitingmaßnahmen und Imagepflege an den Hochschulen. Voraussetzung dafür ist eine enge Zusammenarbeit von Unternehmen und Hochschulen. Hochschuleigener Career Center nach amerikanischem Vorbild übernehmen dabei die Rolle des Vermittlers. Die Gründung von Career Centern und das Angebot von Career Services werden von der Hochschulrektorenkonferenz und der Kultusministerkonferenz als wichtiges Element zur Entwicklung der Employability gefordert.
Background
Alzheimer’s disease (AD) is diagnosed based upon medical history, neuropsychiatric examination, cerebrospinal fluid analysis, extensive laboratory analyses and cerebral imaging. Diagnosis is time consuming and labour intensive. Parkinson’s disease (PD) is mainly diagnosed on clinical grounds.
Objective
The primary aim of this study was to differentiate patients suffering from AD, PD and healthy controls by investigating exhaled air with the electronic nose technique. After demonstrating a difference between the three groups the secondary aim was the identification of specific substances responsible for the difference(s) using ion mobility spectroscopy. Thirdly we analysed whether amyloid beta (Aβ) in exhaled breath was causative for the observed differences between patients suffering from AD and healthy controls.
Methods
We employed novel pulmonary diagnostic tools (electronic nose device/ion-mobility spectrometry) for the identification of patients with neurodegenerative diseases. Specifically, we analysed breath pattern differences in exhaled air of patients with AD, those with PD and healthy controls using the electronic nose device (eNose). Using ion mobility spectrometry (IMS), we identified the compounds responsible for the observed differences in breath patterns. We applied ELISA technique to measure Aβ in exhaled breath condensates.
Results
The eNose was able to differentiate between AD, PD and HC correctly. Using IMS, we identified markers that could be used to differentiate healthy controls from patients with AD and PD with an accuracy of 94%. In addition, patients suffering from PD were identified with sensitivity and specificity of 100%. Altogether, 3 AD patients out of 53 participants were misclassified. Although we found Aβ in exhaled breath condensate from both AD and healthy controls, no significant differences between groups were detected.
Conclusion
These data may open a new field in the diagnosis of neurodegenerative disease such as Alzheimer’s disease and Parkinson’s disease. Further research is required to evaluate the significance of these pulmonary findings with respect to the pathophysiology of neurodegenerative disorders.
With the progress of technology in modern hospitals, an intelligent perioperative situation recognition will gain more relevance due to its potential to substantially improve surgical workflows by providing situation knowledge in real-time. Such knowledge can be extracted from image data by machine learning techniques but poses a privacy threat to the staff’s and patients’ personal data. De-identification is a possible solution for removing visual sensitive information. In this work, we developed a YOLO v3 based prototype to detect sensitive areas in the image in real-time. These are then deidentified using common image obfuscation techniques. Our approach shows that it is principle suitable for de-identifying sensitive data in OR images and contributes to a privacyrespectful way of processing in the context of situation recognition in the OR.
Digitalization changes the manufacturing dramatically. In regard of employees’ demands, global trends and the technological vision of future factories, automotive manufacturing faces a huge number of diverse challenges. Currently, research focuses on technological aspects of future factories in terms of digitalization. New ways of work and new organizational models for future factories have not been described yet. There are assumptions on how to develop the organization of work in a future factory but up to now, literature shows deficits in scientifically substantiated answers in this research area. Consequently, the objective of this paper is to present an approach on a work organization design for automotive Industry 4.0 manufacturing. Future requirements were analyzed and deducted to criteria that determine future agile organization design. These criteria were then transformed into functional mechanisms, which define the approach for shopfloor organization design
Organisationen sind immer mehr gefragt, auch digitale Arbeitsumgebungen bewusst zu formen. Neue Technologien und digitale Arbeitspraktiken verlagern den Ort, an dem eine gemeinsame Identität gebildet wird, zunehmend in virtuelle Räume. Bislang fokussieren sich Führungskräfte und Change Manager jedoch zu sehr auf Dinge, die sie anfassen und plastisch gestalten können. Die Autoren erörtern daher, wie Unternehmen auch in virtuellen Arbeitswelten die organisationale Identität gestalten und aufrechterhalten können, um auf diese Weise das Change Management zu unterstützen.
The powder coating of veneered particle boards by the sequence electrostatic powder application -powder curing via hot pressing is studied in order to create high gloss surfaces. To obtain an appealingaspect, veneer Sheets were glued by heat and pressure on top of particle boards and the resulting surfaceswere used as carrier substrates for powder coat finishing. Prior to the powder coating, the veneeredparticle board surfaces were pre-treated by sanding to obtain good uniformity and the boards werestored in a climate chamber at controlled temperature and humidity conditions to adjust an appropriate electrical surface resistance. Characterization of surface texture was done by 3D microscopy. The surfaceelectrical resistance was measured for the six veneers before and after their application on the particleboard surface. A transparent powder top-coat was applied electrostatically onto the veneered particleboard surface. Curing of the powder was done using a heated press at 130◦C for 8 min and a smooth, glossy coating was obtained on the veneered surfaces. By applying different amounts of powder thecoating thickness could be varied and the optimum amount of powder was determined for each veneer type.
In the powder coating of veneered particle boards the highly reactive hybrid epoxy/polyester powder transparent Drylac 530 Series from TIGER Coatings GmbH & Co. KG, Wels, Austria was used. Curing is accelerated by a mixture of catalysts reaching curing times of 3 min at 150 °C or 5 min at 135 °C which allows for energy and time savings making Drylac Series 530 powder suitable for the coating of temperaturesensitive substrates such as MDF and wood.
Decorative laminates based on melamine formaldehyde (MF) resin impregnated papers are used at great extent for surface finishing of engineered wood that is used for furniture, kitchen, and working surfaces, flooring and exterior cladding. In all these applications, optically flawless appearance is a major issue. The work described here is focused on enhancing the cleanability and antifingerprint properties of smooth, matt surface-finished melamine-coated particleboards for furniture fronts, without at the same time changing or deteriorating other important surface parameters such as hardness, roughness or gloss. In order to adjust the surface polarity of a low pressure melamine film, novel interface-active macromolecular compounds were prepared and tested for their suitability as an antifingerprint additive. Two hydroxy-functional surfactants (polydimethysiloxane, PDMS-OH and perfluoroether, PF-OH) were oxidized under mild conditions to the corresponding aldehydes (PDMS-CHO and PF-CHO) using a pyridinium chlorochromate catalyst. With the most promising oxidized polymeric additive, PDMS-CHO, the contact angles against water, n-hexadecane, and squalene increased from 79.8°, 26.3° and 31.4° for the pure MF surface to 108.5°, 54.8°, and 59.3°, respectively, for the modified MF surfaces. While for the laminated MF surface based on the oxidized fluoroether the gloss values were much higher than required, for the surfaces based on oxidized polydimethylsiloxane the technological values as well as the lower gloss values were in agreement with the requirements and showed much improved surface cleanability, as was also confirmed by colorimetric measurements.
Unprecedented formation of sterically stabilized phospholipid liposomes of cuboidal morphology
(2021)
Sterically stabilized phospholipid liposomes of unprecedented cuboid morphology are formed upon introduction in the bilayer membrane of original polymers, based on polyglycidol bearing a lipid-mimetic residue. Strong hydrogen bonding in the polyglycidol sublayers creates attractive forces, which, facilitated by fluidization of the membrane, bring about the flattening of the bilayers and the formation of cuboid vesicles.
Theoretical foundation, effectiveness, and design artefact for machine learning service repositories
(2022)
Machine learning (ML) has played an important role in research in recent years. For companies that want to use ML, finding the algorithms and models that fit for their business is tedious. A review of the available literature on this problem indicates only a few research papers. Given this gap, the aim of this paper is to design an effective and easy-to-use ML service repository. The corresponding research is based on a multi-vocal literature analysis combined with design science research, addressing three research questions: (1) How is current white and gray literature on ML services structured with respect to repositories? (2) Which features are relevant for an effective ML service repository? (3) How is a prototype for an effective ML service repository conceptualized? Findings are relevant for the explanation of user acceptance of ML repositories. This is essential for corporate practice in order to create and use ML repositories effectively.
The tale of 1000 cores: an evaluation of concurrency control on real(ly) large multi-socket hardware
(2020)
In this paper, we set out the goal to revisit the results of “Starring into the Abyss [...] of Concurrency Control with [1000] Cores” and analyse in-memory DBMSs on today’s large hardware. Despite the original assumption of the authors, today we do not see single-socket CPUs with 1000 cores. Instead multi-socket hardware made its way into production data centres. Hence, we follow up on this prior work with an evaluation of the characteristics of concurrency control schemes on real production multi-socket hardware with 1568 cores. To our surprise, we made several interesting findings which we report on in this paper.
In this paper, we propose a radical new approach for scale-out distributed DBMSs. Instead of hard-baking an architectural model, such as a shared-nothing architecture, into the distributed DBMS design, we aim for a new class of so-called architecture-less DBMSs. The main idea is that an architecture-less DBMS can mimic any architecture on a per-query basis on-the-fly without any additional overhead for reconfiguration. Our initial results show that our architecture-less DBMS AnyDB can provide significant speedup across varying workloads compared to a traditional DBMS implementing a static architecture.
In our initial DaMoN paper, we set out the goal to revisit the results of “Starring into the Abyss [...] of Concurrency Control with [1000] Cores” (Yu in Proc. VLDB Endow 8: 209-220, 2014). Against their assumption, today we do not see single-socket CPUs with 1000 cores. Instead, multi-socket hardware is prevalent today and in fact offers over 1000 cores. Hence, we evaluated concurrency control (CC) schemes on a real (Intel-based) multi-socket platform. To our surprise, we made interesting findings opposing results of the original analysis that we discussed in our initial DaMoN paper. In this paper, we further broaden our analysis, detailing the effect of hardware and workload characteristics via additional real hardware platforms (IBM Power8 and 9) and the full TPC-C transaction mix. Among others, we identified clear connections between the performance of the CC schemes and hardware characteristics, especially concerning NUMA and CPU cache. Overall, we conclude that no CC scheme can efficiently make use of large multi-socket hardware in a robust manner and suggest several directions on how CC schemes and overall OLTP DBMS should evolve in future.
In this paper, we present a new approach for achieving robust performance of data structures making it easier to reuse the same design for different hardware generations but also for different workloads. To achieve robust performance, the main idea is to strictly separate the data structure design from the actual strategies to execute access operations and adjust the actual execution strategies by means of so-called configurations instead of hard-wiring the execution strategy into the data structure. In our evaluation we demonstrate the benefits of this configuration approach for individual data structures as well as complex OLTP workloads.
Ethik im Sportmarketing
(2013)
In diesem Kapitel werden die wichtigsten Begriffe und Grundlagen der Wirtschaftsethik und des Wertemanagements erläutert und auf den Bereich des Sports übertragen. Nach einer kurzen Einführung in die Terminologie werden in einem allgemeinen Teil zunächst die Grundlagen der Wirtschaftsethik beschrieben. Anschließend wird näher auf den Bereich des Wertemanagement eingegangen. Es wird zum einen beschrieben, in welchem Spannungsfeld sich Ethik und Sportmarketing befindet und zum anderen aufzeigt, inwiefern sich Ethik im Sportmarketing von der allgemeinen Wirtschaftsethik unterscheidet. In den darauffolgenden Abschnitten wird an realen Beispielen erläutert, wie Sportorganisation ethikorientiertes Management und vor allem Marketing in ihrer Sportart integrieren und diese zur Stärkung ihrer Position nutzen können. Abgerundet wird dieses Kapitel mit einer Fallstudie, die sich mit Ethik und Marketing bei dem Weltfußballverband FIFA beschäftigt.
This booklet will give you an overview of the development of CSR from a (brief) historic point of view and will examine the underlying concepts and research. Furthermore, examples of contemporary CSR management will be explored to show how companies Interpret the issue and how they face the challenges of managing the new demands placed upon them. Business, in the end, comes down to figures and numbers which give management, shareholders and stakeholders a chance to measure a company’s success. Therefore, modern methods and approaches for measuring, rating and ranking a company’s CSR management will be presented. Finally, an attempt will be made to evaluate CSR as a tool for increasing global welfare and as a business and management strategy for companies and entrepreneurs.