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To improve the energy conversion efficiency of solar organic cells, the clue may lie in the development of devices inspired by an efficient light harvesting mechanism of some aquatic photosynthetic microorganisms that are adapted to low light intensity. Consequently, we investigated the pathways of excitation energy transfer (EET) from successive light harvesting pigments to the low energy level inside the phycobiliprotein antenna system of Acaryochloris marina, a cyanobacterium, using a time resolved absorption difference spectroscopy with a resolution time of 200 fs. The objective was to understand the actual biochemical process and pathways that determine the EET mechanism. Anisotropy of the EET pathway was calculated from the absorption change trace in order to determine the contribution of excitonic coupling. The results reveal a new electron energy relaxation pathway of 14 ps inside the phycocyanin component, which runs from phycocyanin to the terminal emitter. The bleaching of the 660 nm band suggests a broader absorption of the terminal emitter between 660 nm and 675 nm. Further, there are trimer depolarization kinetics of 450 fs and 500 fs in high and low ionic strength, respectively, which arise from the relaxation of the β84 and α84 in adjacent monomers of phycocyanin. Under conditions of low ionic strength buffer solution, the evolution of the kinetic amplitude during the depolarization of the trimer is suggestive of trimer conservation within the phycocyanin hexamer. The anisotropy values were 0.38 and 0.40 in high and in low ionic strength, respectively, indicating that there is no excitonic delocalization in the high energy level of phycocyanin hexamers.
We investigated the excitation modes of the light-harvesting protein phycocyanin (PC) from Thermosynechococcus vulcanus in the crystalline state using UV and near-infrared Raman spectroscopy. The spectra revealed the absence of a hydrogen out-of-plane wagging (HOOP) mode in the PC trimer, which suggests that the HOOP mode is activated in the intact PC rod, while it is not active in the PC trimer. Furthermore, in the PC trimer an intense mode at 984 cm−1 is assigned to the C–C stretching vibration while the mode at 454 cm−1 is likely due to ethyl group torsion. In contrast, in the similar chromophore phytochromobilin the C5,10,15-D wag mode at 622 cm−1 does not come from a downshift of the HOOP. Additionally, the absence of modes between 1200 and 1300 cm−1 rules out functional monomerization. A correlation between phycocyanobilin (PCB) and phycoerythrobilin (PEB) suggests that the PCB cofactors of the PC trimer appear in a conformation similar to that of PEB. The conformation of the PC rod is consistent with that of the allophycocyanin (APC) trimer, and thus excitonic flow is facilitated between these two independent light harvesting compounds. This excitonic flow from the PC rod to APC appears to be modulated by the vibration channels during HOOP wagging, C = C stretching, and the N–H rocking in-plan vibration.
Energy transfer kinetics in photosynthesis as an inspiration for improving organic solar cells
(2017)
Clues to designing highly efficient organic solar cells may lie in understanding the architecture of light harvesting systems and exciton energy transfer (EET) processes in very efficient photosynthetic organisms. Here, we compare the kinetics of excitation energy tunnelling from the intact phycobilisome (PBS) light harvesting antenna system to the reaction center in photosystem II in intact cells of the cyanobacterium Acaryochloris marina with the charge transfer after conversion of photons into photocurrent in vertically aligned carbon nanotube (va- CNT) organic solar cells with poly(3-hexyl)thiophene (P3HT) as the pigment. We find that the kinetics in electron hole creation following excitation at 600 nm in both PBS and va-CNT solar cells to be 450 and 500 fs, respectively. The EET process has a 3 and 14 ps pathway in the PBS, while in va-CNT solar cell devices, the charge trapping in the CNT takes 11 and 258 ps. We show that the main hindrance to efficiency of va CNT organic solar cells is the slow migration of the charges after exciton formation.
The deterioration of the shielding performance of electromagnetic interference finger stock gaskets in a corrosive environment is investigated. The visualization of the real contact area shows a drastic reduction of the engaged active contact region between fingers and their mating surfaces in presence of corrosives residues. In fact, additional openings occur besides the “Tlike” holes due to the porous nature of gaskets. This leads to a strong degradation of the shielding effectiveness. Modified Bethe’s theory is used to estimate the equivalent circuit parameters while the shielding effectiveness in terms of ratio between two transfer functions is obtained upon applying the filter theory. Quantitative measurements carried out for different gasket types show a good agreement with calculated results, demonstrating thus the validity of the approach.
Although spiral antennas have undergone continuous development and refinement since Edwin Turner conceived them in 1954, only a few compact planar arrays exist. The shortcoming is even more significant when it comes to spiral antenna arrays in mode M2 operation. The present work addresses this issue, among other things. It presents two planar arrays of spiral antennas operating in the same frequency band and radiating for the first one an axial mode M1 and a conical mode M2 for the second. Both arrays are modeled, simulated, and fed with a corporate feeding network embedded in a dielectric substrate. It is shown that keeping the same topology, the array for conical M1 mode can be obtained from the array for mode M2 by a simple introduction of a phase shift on one branch of the feed and vice versa, providing thus the possibility to obtain in the same structure a spiral antenna array operating in both modes in the same frequency band simultaneously. Comparison between simulated and measured data shows good agreement.
A new planar compact antenna composed of two crossed Cornu spirals is presented. Each Cornu spiral is fed from the center of the linearly part of the curvature between the two spirals, which builds the clothoid. Sequential rotation is applied using a sequential phase network to obtain circular polarization and increase the effective bandwidth. Signal integrity issues have been addressed and designed to ensure high quality of signal propagation. As a result, the antenna shows good radiation characteristics in the bandwidth of interest. Compared to antennas of the same size in the literature, it is broadband and of high gain. Although the proposed antenna has been designed for K- and Ka-band operations, it can also be developed for lower and upper frequencies because of the linearity of the Maxwell equations.
A methodology for designing planar spiral antennas with a feeding network embedded within a dielectric is presented. To avoid a purely academic work which may not be manufactured with available standard technologies, the approach takes into account manufacturing process requirements by choice of used materials in the simulation. General design rules are provided. They encompass amongst others, selection criteria for dielectric material, aspects to consider when sketching the radiating element design, as well as those for the implementation of the feeding network. A rule of thumb, which maybe helpful in the determination of the antenna supporting substrate’s height, has been found. The appeal of the method resides in the fact that it eases up the design process and helps to minimize errors, saving time and money. The approach also enables the design of a compact and small-size spiral antenna as antenna-in-package (AiP), and provides the opportunity to assemble the antenna with other RF components/systems on the same layer stack or on the same integration platform.
We present a topology of MIMO arrays of inductive antennas exhibiting inherent high crosstalk cancellation capabilities. A single layer PCB is etched into a 3-channels array of emitting/receiving antennas. Once coupled with another similar 3-channels emitter/receiver, we measured an Adjacent Channel Rejection Ratio (ACRR) as high as 70 dB from 150 Hz to 150 kHz. Another primitive device made out of copper wires wound around PVC tubes to form a 2-channels “non-contact slip-ring” exhibited 22 dB to 47 dB of ACRR up to 15MHz. In this paper we introduce the underlying theoretical model behind the crosstalk suppression capabilities of those so-called “Pie-Chart antennas”: an extension of the mutual inductance compensation method to higher number of channels using symmetries. We detail the simple iterative building process of those antennas, illustrate it with numerical analysis and evaluate there effectiveness via real experiments on the 3-channels PCB array and the 2-channels rotary array up to the limit of our test setup. The Pie Chart design is primarily intended as an alternative solution to costly electronic filters or cumbersome EM shields in wireless AND wired applications, but not exclusively.