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Flame-retardant finishing of cotton fabrics using DOPO functionalized alkoxy- and amido alkoxysilane
(2023)
In the present study, DOPO-based alkoxysilane (DOPO-ETES) and amido alkoxysilane (DOPO-AmdPTES) were synthesized by one-step and without by-products as halogen-free flame retardants. The flame retardants were applied on cotton fabric utilizing sol–gel method and pad-dry-cure finishing process. The flame retardancy, the thermal stability and the combustion ehaviour of treated cotton were evaluated by surface and bottom edge ignition flame test (according to EN ISO 15025), thermogravimetric analysis (TGA) and micro-scale combustion calorimeter (MCC). Unlike CO/DOPO-ETES sample, cotton treated with DOPO-AmdPTES nanosols exhibits self-extinguishing ehaviour with high char residue, an improvement of the LOI value and a significant reduction of the PHRR, HRC and THR compared to pristine cotton. Cotton finished with DOPO-AmdPTES reveals a semi-durability after ten laundering cycles keeping the flame-retardant properties unchanged. According to the results obtained from TGA-FTIR, Py-GC/MS and XPS, the major activity of flame retardant occurs in the condensed phase via catalytic induced char formation as physical barrier along with the activity in the gas phase derived mainly from the dilution effect. The early degradation of CO/DOPO-AmdPTES compared to CO/DOPO-ETES, triggered by the cleavage of the weak bond between P and C=O, as the DFT study indicated, provides the beneficial effect of this flame retardant on the fire resistance of cellulose.
Seit 10 Jahren lehrt der Künstler Henning Eichinger an der Hochschule Reutlingen. Was als künstlerische Unterstützung für Textil- und Modedesign-Studenten begann, hat sich mittlerweile zu einer ganz eigenständigen Position entwickelt. Aus dem Designstudium sind einige national und international erfolgreiche junge Künstler und Designer hervorgegangen. Sieben von ihnen werden zusammen mit Henning Eichinger in der Ausstellung präsentiert.
Purpose: The purpose of this study was to investigate the value of the web representation of certain fashion hot spots and how these results can be shown on fashion maps in an illustrated way.
Design/methodology/approach: A new ranking was created, which was evaluated with a self-instructed index, to gain solid results. Numbers were collected from Google, Instagram, Facebook, Twitter and web.alert.io. Additionally, fashion maps were created for an illustrative visualization of the results.
Findings: Compared with the ranking of a trend forecasting agency, called Global Language Monitor, which concepted a ranking of non-virtual fashion cities, the web representation and therefore the ranking of the research project, differs mainly in the situation of the cities among the first 10, viz. the rank on which a city occurs, but fewer in the actual cities mentioned.
Research limitations: The research was limited to subjective analysis of data, leading to partly subjective results, as well as the selected number of social media platforms, that had been used.
Originality/value: This is the first study to explore the web representation value of fashion metropolises in comparison to their non-virtual ranking. The results are partly based on results that already existed, concerning transformations of fashion cities or in general which cities own the status of a fashion city.
Die Ausrüstung von Textilien mit Sol-Gel-Beschichtungen wird seit einigen Jahren intensiv verfolgt. Eine Vielzahl von bekannten, aber auch neuen Ausrüstungseffekten können über diesen Ansatz realisiert werden. Besonders interessant ist die Sol-Gel-Technik wegen der Möglichkeiten, multifunktionelle Ausrüstungen zu synthetisieren. Problematisch ist eine in vielen Fällen geringe Beständigkeit solcher Ausrüstungen, insbesondere gegenüber Waschprozessen. Ziel des Projektes war es davon ausgehend, Vorbehandlungsstrategien für textile Fasermaterialien, basierend auf synthetischen Polymeren oder aus Naturfasern, zu entwickeln, die die Haltbarkeit von Sol-Gel-basierten Ausrüstungen verbessern. Im Rahmen der Arbeiten wurden, angepasst an die jeweiligen Faserpolymere - Polyethylenterephthalat, Polyamid, Polypropylen und Baumwolle - funktionelle Gruppen über geeignete Anker auf den Polymeren etabliert, die in der Lage sind, kovalente Bindungen zu Sol-Gel-basierten Beschichtungssystemen auszubilden. Als Anker wurden primär Trialkoxysilane verwendet, die zusätzlich z.B. Epoxy-, Isocyanato-, Azido- oder Amino-funktionelle Reste besitzen. Mit diesen Resten können die Anker kovalent an die Polymere angebunden werden. Die meisten Sol-Gel-basierten Systeme enthalten zumindest zu einem gewissen Anteil SiOx und/oder MexOy-Cluster. Die zur Funktionalisierung der Oberflächen eingesetzten Alkoxysilane können generell an solche Systeme/Cluster per Kondensation gebunden werden und dienen daher für die effektive Anbindung verschiedenster funktioneller Sol-Gel-Schichten. Entsprechend vorfunktionalisierte Substrate wurden in der Folge mit exemplarisch ausgewählten Sol-Gel-Ausrüstungen beschichtet. Dabei wurden für den Großteil der Untersuchungen hydrophobierende Sole appliziert. Vorteilhaft ist, dass sich der mit hydrophobierenden Solen erzielte Ausrüstungseffekt genau wie dessen Beständigkeit mit vergleichsweise überschaubarem Aufwand über die Untersuchung der Benetzbarkeit (DuPont-Noten, Kontaktwinkel, Tropfeneinsinkzeiten) charakterisieren lässt. Die Wirksamkeit der Vorbehandlungen wurde dann vor allem anhand von Untersuchungen zur Waschbeständigkeit der Ausrüstungen überprüft. Im Rahmen der Arbeiten konnte gezeigt werden, dass sich über die Etablierung geeigneter Anker die Beständigkeit von Sol-Gel-Ausrüstungen bzw. der daraus hervorgehenden Effekte verbessern lässt. Es zeigt sich gleichzeitig, dass die erzielten Verbesserungen sehr stark vom jeweiligen Sol abhängen. D.h., dass sich erzielte Verbesserungen nicht zwangsläufig auf andere Sol übertragen lassen. Analytische Charakterisierungen weisen darauf hin, dass in vielen Fällen die Beständigkeit der Beschichtungsnetzwerke selbst einen weit größeren Einfluss besitzt als die Anbindung an das Substrat. So zeigt sich bei verschiedenen Untersuchungen, dass die Auflage der Sol-Gel-Beschichtung vor allem nach einer ersten Wäsche, aber auch darüber hinaus, signifikant sinkt, oftmals aber ohne dass der durch Ausrüstung erzielte Effekt verloren geht. Dies deutet auf ein (Auf-)Lösen der Beschichtungsmatrizes hin, wovor die Anker nicht schützen können, da deren Wirkung auf die Grenzfläche zum Substrat beschränkt ist. Neben den hydrophobierenden Ausrüstungen wurden exemplarisch auch antibakterielle Ausrüstungen nach den entsprechenden Vorbehandlungen appliziert. Auch hier konnten Verbesserungen in der Beständigkeit des Effektes erzielt werden. Abschließend wurde untersucht inwieweit sich die Vorbehandlungen im Vergleich zur einfachen Ausrüstung negativ auf die textilen Produkte auswirken. Hierzu wurden relevante textile Parameter wie z.B. Höchstzugkräfte, Weißgrade, Steifigkeit oder Luftdurchlässigkeiten bestimmt. Diese Parameter wurden in der überwiegenden Zahl der Vorbehandlungen nicht oder nur geringfügig beeinflusst.
In the luxury Fashion industry, consumers could be categorized into two groups: fashion leader and Fashion follower. Both groups of consumers purchase luxury fashion products aim at satisfying both their functional needs and social needs (i.e., social influence). Thus the demands of both consumer groups are related. In this paper, we construct a model to examine the effects of pricing and online retail service in luxury fashion firms with social influence. To maximize profit, we identify the optimal prices and online retail service when the luxury fashion firms provide the non-differentiated and differentiated online retail services, respectively. More insights are discussed.
It is widely recognized that Education for Sustainable Development (ESD) plays a critical role in creating a more sustainable world by fostering the development of the knowledge, skills, understanding, values, and actions necessary for such change (UNESCO, 2020). In this context, ESD represents a holistic approach that focuses on lifelong learning to create informed people who can make decisions today and in the future. Related to the textile and fashion industry, ESD is an appropriate approach to continuously implement sustainability aspects in education and training. To achieve this goal, the European project "Sustainable Fashion Curriculum at Textile Universities in Europe - Development, Implementation and Evaluation of a Teaching Module for Educators" (Fashion DIET) has developed a digital teaching module in a partnership between a University of Education and universities with textile departments. The main objective of the project is to elaborate an ESD module for university lecturers in order to introduce a sustainable fashion curriculum in textile universities in Europe and implement it in educational systems. The project therefore aims to train educators along the textile supply chain, to inform the young generation about the latest aspects of sustainability and raise awareness by implementing ESD in textile education. This paper presents the learning outcomes of the modules on sustainable fashion design and related production technologies developed by the technical university partners, as part of the total of 42 courses covering didactic-methodological approaches and the sustainable orientation of the fashion market, offered at the consortium level. The project content is made available as Open Educational Resources through Glocal Campus, an open-access e-learning platform that enables virtual collaboration between universities.
The strong demand for a transformation of the textile and fashion industry towards sustainability requires a continuous implementation of the guiding principle of Education for Sustainable Development (ESD) in education and industry [1, 2]. In a first step of the European research project "Sustainable fashion curriculum at textile Universities in Europe - Development, Implementation and Evaluation of a Teaching Module for Educators" (Fashion DIET) a continuing education module shall be created to implement ESD as a guiding principle in university teaching. The research-based teaching and learning materials are delivered through an e-learning portal.
The strong demand to transform the textile and fashion industry towards sustainability requires continuous implementation of the Education for Sustainable Development (ESD) mission statement in education and industry. To achieve this goal, the European research project "Fashion DIET - Sustainable Fashion Curriculum at Textile Universities in Europe. Development, Implementation and Evaluation of a Teaching Module for Educators", co-funded by the Erasmus+ programme of the European Union (2020-1-DE01-KA203-005657), aims to create an ESD module for university lecturers and research-based teaching and learning materials delivered through an e-learning portal. First, an online questionnaire was rolled out to assess university faculty attitudes toward and needs for ESD content and methods. The feedback questionnaire enabled the selection of the most relevant data for the elaboration of an action and research-oriented professional development module for ESD in textile education, which will be accessible through an information & e-learning portal. The e-learning portal can be used as a web-based tool to apply and evaluate the project outcomes, e.g. the further education module and the teaching and learning materials for educators, such as manuals, broadcasts and the provision of interactive and physical materials. It thus ensures that the teaching materials can be used sustainably in the classroom. It also provides country-specific data for the fashion and textile industry and its market, taking into account the different perspectives of universities and schools. In any case, the portal represents (1) the web-based platform to support the dissemination of ESD as a guiding principle and (2) a central contact point for the target group to obtain relevant information on ESD. Fashion DIET explores the use of e-learning to improve teaching and learning on ESD, by training educators and empowering them as multipliers for a sustainable textile and fashion industry. At a higher level, the European project strengthens the quality and relevance of learning provision in education towards the latest developments in textile research and innovation in terms of a more sustainable fashion.
This research is about Omnichannel Retailing and addresses the question how the omnichanneling of retailers in the fashion market can be measured. Our sources will include books, interviews, newspapers and scientific databases.
Omnichanneling is a current topic in the fashion market, retailers all over the world face the question on how to adapt to the challenges Omnichannel Retailing sets. We are going to define what Omnichanneling is by explaining the differences between Multiple-, Multi-, Cross- and Omnichannel Retailing. After we defined omnichanneling itself, we took a set of 26 retailers to evaluate regarding their Omnichannel capabilities. Then we create an index with criteria that can measure the Omnichannel capability of each retailer.
The Omnichannel Score is based on 31 criteria, which analyze the retailers in offline, online, mobile and social aspects enables to see differences between retailers. Our findings were that retailers in the US fashion market are more advanced in Omnichannel Retailing than retailers in the German fashion market. Our top three Omnichannel retailers were Sears with an Omnichannel Score of 91, followed by KOHL’S and Marks&Spencer, both with a Omnichannel Score of 88. The best Omnichannel Retailer from Germany was Adidas with the fourth place and an Omnichannel Score of 81.
Patterns are virtually simulated in 3D CAD programs before production to check the fit. However, achieving lifelike representations of human avatars, especially regarding soft tissue dynamics, remains challenging. This is mainly since conventional avatars in garment CAD programs are simulated with a continuous hard surface and not corresponding to the human physical and mechanical body properties of soft tissue. In the real world, the human body’s natural shape is affected by the contact pressure of tight-fitting textiles. To verify the fit of a simulated garment, the interactions between the individual body shape and the garment must be considered. This paper introduces an innovative approach to digitising the softness of human tissue using 4D scanning technology. The primary objective of this research is to explore the interactions between tissue softness and different compression levels of apparel, exerting pressure on the tissue to capture the changes in the natural shape. Therefore, to generate data and model an avatar with soft body physics, it is essential to capture the deform ability and elasticity of the soft tissue and map it into the modification options for a simulation. To aim this, various methods from different fields were researched and compared to evaluate 4D scanning as the most suitable method for capturing tissue deformability in vivo. In particular, it should be considered that the human body has different deformation capabilities depending on age, the amount of muscle and body fat. In addition, different tissue zones have different mechanical properties, so it is essential to identify and classify them to back up these properties for the simulation. It has been shown that by digitising the obtained data of the different defined applied pressure levels, a prediction of the deformation of the tissue of the exact person becomes possible. As technology advances and data sets grow, this approach has the potential to reshape how we verify fit digitally with soft avatars and leverage their realistic soft tissue properties for various practical purposes.