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Comparative analysis of the chemical and rheological curing kinetics of formaldehyde-based wood adhesives is crucial for assessing their respective performance. Differential scanning calorimetry (DSC) and rheometry are the conventional techniques used for monitoring the curing processes leading to crosslinking polymerization of the adhesives. However, the direct comparison of these techniques is inappropriate due to the intrinsic differences in their underlying procedures. To address this challenge, the two adhesive samples were sequentially cured, firstly with rheometry and followed by DSC. The observed higher curing degree in the subsequent DSC procedure underpins the incomplete curing of the samples during initial rheometry. Furthermore, the comparative assessment of the activation energies, molar ratios, and active groups of the two adhesives highlights the importance of the pre-exponential factor in addition to the activation energies, as it attributes to the probability of active groups coinciding at the appropriate spatial arrangement.
Salivary gland tumors (SGTs) are a relevant, highly diverse subgroup of head and neck tumors whose entity determination can be difficult. Confocal Raman imaging in combination with multivariate data analysis may possibly support their correct classification. For the analysis of the translational potential of Raman imaging in SGT determination, a multi-stage evaluation process is necessary. By measuring a sample set of Warthin tumor, pleomorphic adenoma and non-tumor salivary gland tissue, Raman data were obtained and a thorough Raman band analysis was performed. This evaluation revealed highly overlapping Raman patterns with only minor spectral differences. Consequently, a principal component analysis (PCA) was calculated and further combined with a discriminant analysis (DA) to enable the best possible distinction. The PCA-DA model was characterized by accuracy, sensitivity, selectivity and precision values above 90% and validated by predicting model-unknown Raman spectra, of which 93% were classified correctly. Thus, we state our PCA-DA to be suitable for parotid tumor and non-salivary salivary gland tissue discrimination and prediction. For evaluation of the translational potential, further validation steps are necessary.
Im Team zum fliegenden Traum
(2024)
Purpose – This paper aims to determine the affecting factors of the brand authenticity of startups in social media.
Design/methodology/approach – Using a qualitative method based on a grounded theory approach, this research specifies and classifies the affecting factors of brand authenticity of startups in social media through in-depth semi-structured interviews.
Findings – Multiple factors affecting the brand authenticity of startups in social media are determined and categorized as indexical, iconic and existential cues through this research. Connection to heritage and having credible support are determined as indexical cues. Founder intellectuality, brand intellectuality, commitment toward customers and proactive clear and interesting communications are identified as iconic cues. Having self-confidence and self-satisfaction, having intimacy with the brand and a joyful feeling for interactions with the community around the brand are determined as existential cues in this research. This research furthers previous arguments on a multiplicity of brand authenticity by shedding light on the relationship between the different aspects of authenticity and the form that different affecting factors can be organized together. Consumers eventually evaluate a strengthened perception of brand authenticity through existential cues that reflect the cues of other aspects (iconic and indexical) which passed through the goal-based assessment and self-authentication filter.
Research limitations/implications – The research sampling population can be more diversified in terms of sociodemographic attributes. Due to the qualitative methodology of this research, assessment of the findings through quantitative methods can be considered in future research. Practical implications – Using the findings of this research, startup managers can properly build a perception of authenticity in their consumers’ minds by using alternate factors while lacking major indexical cues such as heritage. This research helps startup businesses to design their brand communications better to convey their authenticity to their audiences.
Originality/value – This research determines the factors affecting the authenticity of startup brands in social media. It also defines the process of authenticity perception through different aspects of brand authenticity.
Human Digital Twin
(2022)
Man stelle sich vor, man könnte mit Unterstützung von künstlicher Intelligenz Spielabläufe von Bundesligaspielen oder sogar ganze WM-Partien simulieren. Oder der Trainer würde die Mannschaft im Endspiel anhand von Daten über den Gegner aufstellen und entsprechend psychologisch und physiologisch verschiedene Spielertypen auf den Platz schicken (vgl. Jahn). Ist das reine Fiktion? Nicht wirklich. Bereits heute werden die Leistungen von Sportlern immer häufiger digital analysiert und bewertet. Beispielsweise hat SAP eine Plattform entwickelt, die ein digitales Datenbild von Fußballspielern erstellt (vgl. SAP). Bei der letzten WM erhielt jeder Spieler über die neue Fifa Player App kurz nach der Begegnung präzise Statistiken zu seinen Leistungen während des Spiels (vgl. FIFA). Noch bessere Informationen sollen in Zukunft virtuelle Abbilder der Fußballspieler, digitale Zwillinge, liefern. Die dafür notwendigen Daten werden mithilfe von Sensoren im Trikot, in den Schuhen oder im Ball gewonnen. Durch erfassten Bewegungs- und Positionsdaten sowie Ballkontakten entsteht ein präzises Datenbild des Spielers. Solche Simulationen, die auf einem Modell des Menschen in der digitalen Welt beruhen, erfahren derzeit große Aufmerksamkeit in Wissenschaft und Praxis (vgl. van der Valk et al.). Nicht nur in der Fußballwelt, auch in der Medizin und im Kontext von Industrie 4.0 und Produktdesign, haben digitale menschliche Zwillinge das Potenzial, zu einer Schlüsseltechnologie zu werden.
Plasmonics and nanophotonics both deal with the interaction of light with structures of typically sub-wavelength size in one of more dimensions. Over the past decade or two, interest in these topics has grown significantly. This includes basic research towards detailed understanding of light-matter interaction and the manipulation of light on the nanometer scale as well as the search for applications ranging from quantum information processing, data storage, solar cells, spectroscopy and microscopy to (bio-)sensors and biomedical devices. Key enablers for this development are advanced materials and the variety of techniques to structure them with nanometer precision on the one hand, and progress in the theoretical description and numerical implementations, on the other. Besides the traditional metals Au, Ag, Al, and Cu also compounds such as refractory metal nitrides with much higher durability as well as semiconductors, dielectrics and hybrid structures have become of interest. Structuring techniques are not only aiming at the fabrication of individual elements with highest precision for detailed interaction analysis, but also at methods for large scale, low-cost nanofabrication mostly for sensor applications. In the former case, mostly electron beam lithography and focused ion beam milling are employed, while for high throughput various forms of nanoimprint and self-assembly based techniques are favored. Thin film deposition and pattern transfer techniques are mostly derived from those developed for nano-electronics, however more recently methods such as electroless plating, atomic layer deposition or etching and 3-D additive techniques are appearing. Thus, highly specialized expertise has been acquired in the different disciplines, and successful research and technology transfer will draw from this pool of knowledge.
Introduction to the special issue on self‑managing and hardware‑optimized database systems 2022
(2023)
Data management systems have evolved in terms of functionality, performance characteristics, complexity, and variety during the last 40 years. Particularly, the relational database management systems and the big data systems (e.g., Key-Value stores, Document stores, Graph stores and Graph Computation Systems, Spark, MapReduce/Hadoop, or Data Stream Processing Systems) have evolved with novel additions and extensions. However, the systems administration and tasks have become highly complex and expensive, especially given the simultaneous and rapid hardware evolution in processors, memory, storage, or networking. These developments present new open problems and challenges to data management systems as well as new opportunities.
The SMDB (International Workshop on Self-Managing Database Systems) and HardBD&Active (Joint International Workshop on Big Data Management on Emerging Hardware and Data Management on Virtualized Active Systems) workshops organized in conjunction with the IEEE ICDE (International Conference on Data Engineering) offered two distinct platforms for examining the above system-related challenges from different perspectives. The SMDB workshop looks into developing autonomic or self-* features in database and data management systems to tackle complex administrative tasks, while the HardBD&Active workshop focuses on harnessing hardware technologies to enhance efficiency and performance of data processing and management tasks. As a result of these workshops, we are delighted to present the third special issue of DAPD titled “Self-Managing and Hardware-Optimized Database Systems 2022,” which showcases the best contributions from the SMDB 2021/2022 and HardBD&Active 2021/2022 workshops.
Digitalization and enterprise architecture management: a perspective on benefits and challenges
(2023)
Many companies digitally transform their business models, processes, and services. They have also been using Enterprise Architecture Management approaches for a long time to synchronize corporate strategy and information technology. Such digitalization projects bring different challenges for Enterprise Architecture Management. Without understanding and addressing them, Enterprise Architecture Management projects will fail or not deliver the expected value. Since existing research has not yet addressed these challenges, they were investigated based on a qualitative expert study with leading industry experts from Europe. Furthermore, potential benefits of digitalization projects for Enterprise Architecture Management were researched. Our results provide a theoretical framework consisting of five identified challenges, triggers and a number of benefits. Furthermore, we discuss in what ways digitalization and EAM is a promising topic for future research.
In recent years, both fields, AI and VRE, have received increasing attention in scientific research. Thus, this article’s purpose is to investigate the potential of DL-based applications on VRE and as such provide an introduction to and structured overview of the field. First, we conduct a systematic literature review of the application of Artificial Intelligence (AI), especially Deep Learning (DL), on the integration of Variable Renewable Energy (VRE). Subsequently, we provide a comprehensive overview of specific DL-based solution approaches and evaluate their applicability, including a survey of the most applied and best suited DL architectures. We identify ten DL-based approaches to support the integration of VRE in modern power systems. We find (I) solar PV and wind power generation forecasting, (II) system scheduling and grid management, and (III) intelligent condition monitoring as three high potential application areas.
Do Chinese subordinates trust their German supervisors? A model of inter-cultural trust development
(2023)
In this qualitative study based on 95 interviews with Chinese subordinates and their German supervisors, we inductively develop a model which advances theoretical understanding by showing how inter-cultural trust development in hierarchical relationships is the result of six distinct elements: the subordinate trustor’s cultural profile (cosmopolitans, hybrids, culturally bounds), the psychological mechanisms operating within the trustor (role expectations and cultural accommodation), and contextual moderators (e.g., country context, time spent in foreign culture, and third-party influencers), which together influence the trust forms (e.g., presumptive trust, relational trust) and trust dynamics (e.g., trust breakdown and repair) within relationship phases over time (initial contact, trust continuation, trust disillusionment, separation, and acculturation). Our findings challenge the assumption that cultural differences result in low levels of initial trust and highlight the strong role the subordinate’s cultural profile can have on the dynamics and trajectory of trust in hierarchical relationships. Our model highlights that inter-cultural trust development operates as a variform universal, following the combined universalistic-particularistic paradigm in cross-cultural management, with both culturally generalizable etic dynamics, as well as culturally specific etic manifestations.